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- W4220804941 abstract "The diastereo- and enantioselective dearomative formal [3 + 2] cycloaddition of 2-nitrobenzofurans and α-aryl-α-isocyanoacetate esters provides tricyclic compounds bearing the 3a,8b-dihydro-1H-benzofuro[2,3-c]pyrrole framework with three consecutive stereogenic centers. The reaction was enabled by a cupreine-ether organocatalyst. The reaction products were obtained with almost full diastereoselectivity and with excellent enantiomeric excesses for a number of substituted 2-nitrobenzofurans and isocyanoacetates." @default.
- W4220804941 created "2022-04-03" @default.
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- W4220804941 date "2022-03-16" @default.
- W4220804941 modified "2023-10-15" @default.
- W4220804941 title "Metal-Free Diastereo- and Enantioselective Dearomative Formal [3 + 2] Cycloaddition of 2-Nitrobenzofurans and Isocyanoacetate Esters" @default.
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- W4220804941 doi "https://doi.org/10.1021/acs.orglett.2c00427" @default.
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