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• W4220807992 abstract "Abstract 3‐Hydroxypiperidinium pentaiodide was synthesized by a facile reaction in concentrated aqueous HI. Its crystal structure comprises 3‐hydroxypiperidinium cations and pentaiodide anions, the latter having geometry of cis ‐shaped chains composed of I 2 and I 3 − building units. The analysis of interatomic distances, Raman spectroscopy data, and results of DFT calculations, including non‐covalent interaction analysis, showed that the title compound exhibits a complex pattern of covalent and non‐covalent interactions. Those include I−I covalent bonds and I⋅⋅⋅I halogen bonds within the I 5 − anion as well as (N)H⋅⋅⋅I and (O)H⋅⋅⋅I hydrogen bonds and even weaker (C)H⋅⋅⋅I van‐der‐Waals interactions between the cations and anions." @default.
• W4220807992 created "2022-04-03" @default.
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• W4220807992 date "2022-03-16" @default.
• W4220807992 modified "2023-09-27" @default.
• W4220807992 title "Pattern of covalent and non‐covalent interactions within the pentaiodide anion in the structure of (3‐HOC₅H₉NH₂)I₅" @default.
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• W4220807992 doi "https://doi.org/10.1002/zaac.202200039" @default.
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