Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220821370> ?p ?o ?g. }
- W4220821370 endingPage "3180" @default.
- W4220821370 startingPage "3164" @default.
- W4220821370 abstract "Carborynes (1,2-dehydro-o-carborane and 1,3-dehydro-o-carborane), three-dimensional analogues of benzyne, can be generated in situ from the precursors 1-X-2-Li-1,2-C2B10H10 (X = Br, I, OTs, OTf), or 1-Me3Si-2-[IPh(OAc)]-1,2-C2B10H10 or [1-Li-3-N2-1,2-C2B10H10][BF4]. They are a class of very useful synthons for the synthesis of a large variety of functionalized carborane derivatives for potential application in medicine, materials science and organometallic/coordination chemistry. The experimental data demonstrate that there is a correspondence between the reactions of carborynes and those of benzyne with alkenes, dienes, alkynes, aromatics or heteroaromatics in a pericyclic reaction fashion. On the other hand, carborynes have unique properties of their own owing to their steric/electronic features. They undergo regioselective sp2/sp3 C-H bond and N-Li bond insertion reactions, which has not been observed for benzyne. This review provides a comprehensive overview of recent advances in this interesting research field with considerable attention devoted to the reaction modes and the mechanisms involved." @default.
- W4220821370 created "2022-04-03" @default.
- W4220821370 creator A5030076543 @default.
- W4220821370 creator A5078892060 @default.
- W4220821370 date "2022-01-01" @default.
- W4220821370 modified "2023-10-14" @default.
- W4220821370 title "Functionalization of <i>o</i>-carboranes <i>via</i> carboryne intermediates" @default.
- W4220821370 cites W1457805278 @default.
- W4220821370 cites W1823137473 @default.
- W4220821370 cites W1914311389 @default.
- W4220821370 cites W1967340207 @default.
- W4220821370 cites W1979109848 @default.
- W4220821370 cites W1983183730 @default.
- W4220821370 cites W1986453358 @default.
- W4220821370 cites W1994496780 @default.
- W4220821370 cites W1994541961 @default.
- W4220821370 cites W2000076450 @default.
- W4220821370 cites W2002528196 @default.
- W4220821370 cites W2004798939 @default.
- W4220821370 cites W2007138156 @default.
- W4220821370 cites W2011594973 @default.
- W4220821370 cites W2013491451 @default.
- W4220821370 cites W2020813668 @default.
- W4220821370 cites W2022218819 @default.
- W4220821370 cites W2027688618 @default.
- W4220821370 cites W2035348510 @default.
- W4220821370 cites W2037143889 @default.
- W4220821370 cites W2040402142 @default.
- W4220821370 cites W2045501107 @default.
- W4220821370 cites W2057048798 @default.
- W4220821370 cites W2062871747 @default.
- W4220821370 cites W2063627652 @default.
- W4220821370 cites W2068333094 @default.
- W4220821370 cites W2075385283 @default.
- W4220821370 cites W2075926580 @default.
- W4220821370 cites W2080017659 @default.
- W4220821370 cites W2081859392 @default.
- W4220821370 cites W2085304850 @default.
- W4220821370 cites W2086155900 @default.
- W4220821370 cites W2088373686 @default.
- W4220821370 cites W2102095712 @default.
- W4220821370 cites W2107158355 @default.
- W4220821370 cites W2108760670 @default.
- W4220821370 cites W2112281524 @default.
- W4220821370 cites W2124780295 @default.
- W4220821370 cites W2130867856 @default.
- W4220821370 cites W2135027533 @default.
- W4220821370 cites W2144484723 @default.
- W4220821370 cites W2155959796 @default.
- W4220821370 cites W2161359588 @default.
- W4220821370 cites W2162453620 @default.
- W4220821370 cites W2230643548 @default.
- W4220821370 cites W2261916736 @default.
- W4220821370 cites W2315095018 @default.
- W4220821370 cites W2321277936 @default.
- W4220821370 cites W2324937328 @default.
- W4220821370 cites W2325567179 @default.
- W4220821370 cites W2332760494 @default.
- W4220821370 cites W2335316484 @default.
- W4220821370 cites W2343107732 @default.
- W4220821370 cites W2406091788 @default.
- W4220821370 cites W2495813373 @default.
- W4220821370 cites W2513963363 @default.
- W4220821370 cites W2519044780 @default.
- W4220821370 cites W2553518572 @default.
- W4220821370 cites W2584119932 @default.
- W4220821370 cites W2592506240 @default.
- W4220821370 cites W2619461665 @default.
- W4220821370 cites W2620800339 @default.
- W4220821370 cites W2756662710 @default.
- W4220821370 cites W2766313895 @default.
- W4220821370 cites W2786250126 @default.
- W4220821370 cites W2792920788 @default.
- W4220821370 cites W2793629614 @default.
- W4220821370 cites W2795054874 @default.
- W4220821370 cites W2804057211 @default.
- W4220821370 cites W2808253854 @default.
- W4220821370 cites W2889530304 @default.
- W4220821370 cites W2912983862 @default.
- W4220821370 cites W2913914692 @default.
- W4220821370 cites W2949547146 @default.
- W4220821370 cites W2949721965 @default.
- W4220821370 cites W2949842757 @default.
- W4220821370 cites W2950609052 @default.
- W4220821370 cites W2950769491 @default.
- W4220821370 cites W2951369883 @default.
- W4220821370 cites W2951413426 @default.
- W4220821370 cites W2951620617 @default.
- W4220821370 cites W2952765134 @default.
- W4220821370 cites W3002371068 @default.
- W4220821370 cites W3019410271 @default.
- W4220821370 cites W3081378486 @default.
- W4220821370 cites W3087727510 @default.
- W4220821370 cites W3108830835 @default.
- W4220821370 cites W3125304574 @default.
- W4220821370 cites W3130352594 @default.
- W4220821370 cites W3132823191 @default.
- W4220821370 cites W3143588145 @default.