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- W4220831574 abstract "High reactivity of trimethoxyphenyl (TMP)-iodonium(III) acetate for phenol O-arylation was achieved. It was first determined that the TMP ligand and acetate anion cooperatively enhance the electrophilic reactivity toward phenol oxygen atoms. The proposed method provides access to various diaryl ethers in significantly higher yields than the previously reported techniques. Various functional groups, including aliphatic alcohol, boronic ester, and sterically hindered groups, were tolerated during O-arylation, verifying the applicability of this ligand- and counterion-assisted strategy." @default.
- W4220831574 created "2022-04-03" @default.
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- W4220831574 date "2022-03-07" @default.
- W4220831574 modified "2023-10-16" @default.
- W4220831574 title "Ligand- and Counterion-Assisted Phenol <i>O</i>-Arylation with TMP-Iodonium(III) Acetates" @default.
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- W4220831574 doi "https://doi.org/10.1021/acs.orglett.2c00294" @default.
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