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- W4220841855 abstract "Abstract Accelerated aging studies of β CL‐20 thin films deposited on glass surfaces in different environments (N 2 , air, air/water) were conducted. Samples were analyzed with attenuated total reflectance infrared (ATR‐IR) spectroscopy. Spectral features of molecular lattice inclusions in CL‐20 films aged in an air/water environment were observed. The features occurred after β CL‐20 polymorph transformation to α CL‐20 and were accompanied by the appearance of lattice water peaks. To assist ATR‐IR peak assignment, density functional theory studies were performed, and IR spectra of α CL‐20 lattice inclusions of small molecules that were identified as degradation products of CL‐20 were computed. Simulated spectra of NO 2 , HNCO, N 2 O, and CO 2 incorporated into partially hydrated α CL‐20 matched the experimental spectrum of β CL‐20 thin films aged in air/water." @default.
- W4220841855 created "2022-04-03" @default.
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- W4220841855 date "2022-03-22" @default.
- W4220841855 modified "2023-10-03" @default.
- W4220841855 title "Molecular Inclusion of Small Aging Products into the Hexanitrohexaazaisowurtzitane (CL‐20) Lattice: Part I, Infrared Spectra" @default.
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- W4220841855 doi "https://doi.org/10.1002/prep.202100359" @default.
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