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- W4220851593 abstract "A modular approach to prepare tri- and tetracyclic carbazoles by a sequential [3 + 2]heteroannulation is described. First, optimization of Pd-catalyzed Buchwald-Hartwig amination followed by C/N-arylation in a one-pot process is established. Second, mechanistic analyses identified the origins of chemo- and regioselective sequential control of both bond-forming steps. Finally, the substrate scope is demonstrated by the preparation of a range of tri- and tetracyclic carbazoles, including expedient access to several natural products and anti-cancer agents." @default.
- W4220851593 created "2022-04-03" @default.
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- W4220851593 date "2022-03-18" @default.
- W4220851593 modified "2023-09-26" @default.
- W4220851593 title "A Chemo- and Regioselective Tandem [3 + 2]Heteroannulation Strategy for Carbazole Synthesis: Combining Two Mechanistically Distinct Bond-Forming Processes" @default.
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- W4220851593 doi "https://doi.org/10.1021/acs.joc.1c02943" @default.
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