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- W4220852439 abstract "Abstract In the present work, we report on the synthesis of EuSO 4 powders by two different methods using EuS as starting material. The compound EuSO 4 contains divalent europium and crystallizes in the orthorhombic crystal system, space group P nma with parameters close to SrSO 4 . The compound exhibits near isotropic thermal expansion over the temperature range 300–700 K. EuSO 4 was examined by Raman, Fourier‐transform infrared absorption and luminescence spectroscopy methods. EuSO 4 is found to be an indirect bandgap material with a bandgap close to direct electronic transition. The emission lifetime of divalent europium d‐f emission in EuSO 4 shows an unusual behavior for stoichiometric compounds, as it shortens upon cooling from 1.11(1) μs at room temperature to 0.44(1) μs at 77 K." @default.
- W4220852439 created "2022-04-03" @default.
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- W4220852439 date "2022-03-15" @default.
- W4220852439 modified "2023-10-14" @default.
- W4220852439 title "Europium (II) Sulfate EuSO<sub>4</sub>: Synthesis Methods, Crystal and Electronic Structure, Luminescence Properties" @default.
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- W4220852439 doi "https://doi.org/10.1002/ejic.202200043" @default.
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