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• W4220854611 abstract "Gas-phase ion-ion reactions between tris-1,10-phenantholine metal dications, [(phen)3M]2+ (where M = Ni and Mg), and the tetraphenylborate anion yield the ion-pairs {[(phen)3M]2+[BPh4]-}+. The ion-pairs undergo transmetalation upon loss of a phen ligand to give the organometallic complexes [(phen)2M(Ph)]+. DFT calculations, used to determine the energy barriers for the transmetalation reactions and the hydrolysis reactions, are entirely consistent with the experimental results." @default.
• W4220854611 created "2022-04-03" @default.
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• W4220854611 date "2022-01-01" @default.
• W4220854611 modified "2023-09-26" @default.
• W4220854611 title "Ion-pairs as a gateway to transmetalation: aryl transfer from boron to nickel and magnesium" @default.
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• W4220854611 doi "https://doi.org/10.1039/d2dt00746k" @default.
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• W4220854611 hasPublicationYear "2022" @default.
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