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- W4220854741 abstract "Developing cost-/energy-efficient separation techniques for purifying ethylene from an ethylene/ethane mixture is highly important but very challenging in the industrial process. Herein, using a bottom-up [8 + 2] construction approach, we rationally designed and synthesized three three-dimensional covalent organic frameworks (COFs) with 8-connected bcu networks, which can selectively remove ethane from an ethylene/ethane mixture with high efficiency. These COF materials, which are fabricated by the condensation reaction of a customer-designed octatopic aldehyde monomer with linear diamino linkers, possess high crystallinity, good structural robustness, and high porosity. Attributed to the well-organized micro-sized pores with a nonpolar/inert pore environment, these COFs display high ethane adsorption capacity and good selectivity over ethylene, making them among the best ethane-selective adsorbents for ethylene purification. Their excellent ethylene/ethane separation performance is validated by dynamic breakthrough experiments with high-purity ethylene (>99.99%) produced through a single adsorption process. The separation performance surpasses all reported C2H6-selective COFs and even some benchmark metal-organic frameworks. This work provides important guidance for the design of new adsorbents for value-added gas purification." @default.
- W4220854741 created "2022-04-03" @default.
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- W4220854741 date "2022-03-21" @default.
- W4220854741 modified "2023-10-13" @default.
- W4220854741 title "Bottom-Up Synthesis of 8-Connected Three-Dimensional Covalent Organic Frameworks for Highly Efficient Ethylene/Ethane Separation" @default.
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- W4220854741 doi "https://doi.org/10.1021/jacs.2c01058" @default.
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