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- W4220877708 abstract "The scope of chemoselective β-hydride elimination in the context of arylation/alkenylation of homoenolates from cyclopropanol precursors using organoboronic reagents as transmetalation coupling partners was examined. The reaction optimization paradigm revealed a simple ligand-free Pd(II) catalytic system to be most efficient under open air conditions. The preparative scope, which was investigated with 48 examples, supported the applicability of this reaction to a wide range of substrates tolerating a variety of functional groups while delivering β-substituted enone and dienone derivatives in 62-95% yields." @default.
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- W4220877708 date "2022-03-15" @default.
- W4220877708 modified "2023-10-14" @default.
- W4220877708 title "Orchestrating a β-Hydride Elimination Pathway in Palladium(II)-Catalyzed Arylation/Alkenylation of Cyclopropanols Using Organoboron Reagents" @default.
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- W4220877708 doi "https://doi.org/10.1021/acs.joc.1c02735" @default.
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