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- W4220885123 abstract "An original approach has been developed for the insertion of formyl substituents at positions 2 and 5 of 1,4-dihydropyrrolo[3,2-b]pyrroles by conversion of thiazol-2-yl substituents. The synthetic utility of these formyl groups was investigated, and a series of centrosymmetric A-π-D-π-A frameworks were constructed. The two-photon absorption of the quadrupolar pyrrolo[3,2-b]pyrrole possessing two dicyanovinylidene flanking groups is attributed to an S0 → (S1) → S4 transition which has a large TPA cross-section (1300 GM) for a molecule of this size." @default.
- W4220885123 created "2022-04-03" @default.
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- W4220885123 date "2022-03-28" @default.
- W4220885123 modified "2023-09-30" @default.
- W4220885123 title "From 2,5-Diformyl-1,4-dihydropyrrolo[3,2-<i>b</i>]pyrroles to Quadrupolar, Centrosymmetric Two-Photon-Absorbing A–D–A Dyes" @default.
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- W4220885123 doi "https://doi.org/10.1021/acs.orglett.2c00718" @default.
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