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- W4220887509 abstract "Abstract To obtain high yields of hydrogen, a series of Zr x Pr 1–x O y ‐supported cobalt catalysts were synthesized by the sol‐gel method and tested in autothermal reforming (ATR) of acetic acid (HAc) derived from bio‐oil. X‐ray diffraction, nitrogen physisorption, H 2 ‐temperature‐programmed reduction, and thermogravimetric analysis were conducted to investigate the factors affecting the activities of the catalysts. Over the Co‐Zr‐Pr‐O catalyst, a Zr x Pr 1–x O y solid solution was formed after calcination; meanwhile, the active component of Co 0 was highly dispersed over the solid solution after reduction in hydrogen for 1 h at 700 °C. As a result, stable reactivity was recorded in the ATR process of HAc: the hydrogen yield reached 2.58 with near 100 % HAc conversion, while better resistance to coking was observed." @default.
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- W4220887509 date "2022-04-14" @default.
- W4220887509 modified "2023-09-28" @default.
- W4220887509 title "Zr <sub>x</sub> Pr <sub>1−x</sub> O <sub>y</sub> solid solution supported cobalt‐based catalysts for hydrogen production" @default.
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- W4220887509 doi "https://doi.org/10.1002/ceat.202200010" @default.
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