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- W4220921884 abstract "Herein, we report a new metal-organic framework with an AIE ligand (H4TCPP = 2,3,5,6-tetra-(4-carboxyphenyl)pyrazine) and Mg2+ ions, that is, [Mg2(H2O)4TCPP]·DMF·5CH3CN (Mg-TCPP, TCPP = tetra-(4-carboxyphenyl)pyrazine) for detection of nitroaromatic explosives. Due to the coordination effect and restricted intramolecular rotation, Mg-TCPP exhibits bright blue light. As a fluorescent sensor, Mg-TCPP exhibits high selectivity and sensitivity for sensing 2,4,6-trinitrophenol (TNP) by quenching behaviors with the Stern-Volmer quenching constant (KSV) of 3.63×105 L/mol and achieves the low limit of detection of 25.6 ppb, which is beyond most of the previously reported fluorescent materials. Notably, the portable Mg-TCPP films are prepared and it can be used for rapid and sensitive TNP detection in a variety of environments including organic solvent and aqueous solution. Moreover, TNP vapor can be detected within 3 min by naked eye and the film could be regenerated under simple solvent cleaning." @default.
- W4220921884 created "2022-04-03" @default.
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- W4220921884 date "2023-03-01" @default.
- W4220921884 modified "2023-09-28" @default.
- W4220921884 title "Rational design of an AIE-active metal-organic framework for highly sensitive and portable sensing nitroaromatic explosives" @default.
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- W4220921884 doi "https://doi.org/10.1016/j.cclet.2022.03.014" @default.
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