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- W4220922010 abstract "Ruthenium oxide (RuO2) and Polyaniline (PANI) as electrode materials are attracting extensive attention due to their remarkable pseudocapacitance. However, RuO2 suffers from low utilization and PANI sustains poor stability. Herein, the both defects were optimized by design of intercalated structure PANI/RuO2 composites, which were fabricated for the first time by controllable chemical polymerization of aniline on the delaminated RuO2 nanosheets. Intercalated PANI nanofibers not only highly prevent the RuO2 nanosheets from their reassembling as well as increase the interlayer spacing among RuO2 nanosheets, but also alleviate the swelling/shrinking of PANI during charge-discharge progress. In comparison to the pristine RuO2 nanosheets, the obtained intercalated structure is beneficial of creating channels for better ions transfer and electron transport, which lead to a high-efficiency utilization of RuO2 nanosheets. The optimized PANI/RuO2-38 electrode with the RuO2 content of 61.7 wt% shows the highest utilization of 72.1% of RuO2 resulting in the highest specific capacity of 816 F g−1. Asymmetric supercapacitor PANI/RuO2//AC offers high energy density of 25.7 Wh kg−1 at 375 kW kg−1, further indicating a good potential as energy storage device." @default.
- W4220922010 created "2022-04-03" @default.
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- W4220922010 date "2022-05-02" @default.
- W4220922010 modified "2023-09-29" @default.
- W4220922010 title "Controllable Intercalated Polyaniline Nanofibers Highly Enhancing the Utilization of Delaminated RuO <sub>2</sub> Nanosheets for High‐Performance Hybrid Supercapacitors" @default.
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- W4220922010 doi "https://doi.org/10.1002/celc.202200039" @default.
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