Matches in SemOpenAlex for { <https://semopenalex.org/work/W4220933897> ?p ?o ?g. }
- W4220933897 abstract "Abstract In recent years, asymmetric catalysis of ynamides has attracted much attention, but these reactions mostly constructed central chirality, except for a few examples on the synthesis of axially chiral compounds which exclusively relied on noble‐metal catalysis. Herein, a facile access to axially chiral N ‐heterocycles enabled by chiral Brønsted acid‐catalyzed 5‐ endo ‐ dig cyclization of ynamides is disclosed, which represents the first metal‐free protocol for the construction of axially chiral compounds from ynamides. This method allows the practical and atom‐economical synthesis of valuable N ‐arylindoles in excellent yields with generally excellent enantioselectivities. Moreover, organocatalysts and ligands based on such axially chiral N ‐arylindole skeletons are demonstrated to be applicable to asymmetric catalysis." @default.
- W4220933897 created "2022-04-03" @default.
- W4220933897 creator A5000952268 @default.
- W4220933897 creator A5002068991 @default.
- W4220933897 creator A5023229525 @default.
- W4220933897 creator A5023473958 @default.
- W4220933897 creator A5031547714 @default.
- W4220933897 creator A5087744964 @default.
- W4220933897 date "2022-03-16" @default.
- W4220933897 modified "2023-10-16" @default.
- W4220933897 title "Synthesis of Axially Chiral <i>N</i>‐Arylindoles via Atroposelective Cyclization of Ynamides Catalyzed by Chiral Brønsted Acids" @default.
- W4220933897 cites W1518237563 @default.
- W4220933897 cites W1971284614 @default.
- W4220933897 cites W1972631101 @default.
- W4220933897 cites W1985515616 @default.
- W4220933897 cites W2008193102 @default.
- W4220933897 cites W2014740849 @default.
- W4220933897 cites W2023474305 @default.
- W4220933897 cites W2043620462 @default.
- W4220933897 cites W2048094838 @default.
- W4220933897 cites W2050324952 @default.
- W4220933897 cites W2066581574 @default.
- W4220933897 cites W2084790801 @default.
- W4220933897 cites W2160646913 @default.
- W4220933897 cites W2163377997 @default.
- W4220933897 cites W2343563408 @default.
- W4220933897 cites W2548894381 @default.
- W4220933897 cites W2587119560 @default.
- W4220933897 cites W2774581714 @default.
- W4220933897 cites W2787698056 @default.
- W4220933897 cites W2792597494 @default.
- W4220933897 cites W2948495562 @default.
- W4220933897 cites W2948692488 @default.
- W4220933897 cites W2950688863 @default.
- W4220933897 cites W2951112480 @default.
- W4220933897 cites W2962781427 @default.
- W4220933897 cites W2966116423 @default.
- W4220933897 cites W2970851373 @default.
- W4220933897 cites W2972512227 @default.
- W4220933897 cites W2976450650 @default.
- W4220933897 cites W2978601281 @default.
- W4220933897 cites W2990343202 @default.
- W4220933897 cites W2991316349 @default.
- W4220933897 cites W2994781335 @default.
- W4220933897 cites W2999904136 @default.
- W4220933897 cites W3004578117 @default.
- W4220933897 cites W3010981433 @default.
- W4220933897 cites W3014208849 @default.
- W4220933897 cites W3023106324 @default.
- W4220933897 cites W3039976008 @default.
- W4220933897 cites W3082439490 @default.
- W4220933897 cites W3083487592 @default.
- W4220933897 cites W3092932813 @default.
- W4220933897 cites W3096117312 @default.
- W4220933897 cites W3103203737 @default.
- W4220933897 cites W3107909760 @default.
- W4220933897 cites W3110939857 @default.
- W4220933897 cites W3116146439 @default.
- W4220933897 cites W3125557755 @default.
- W4220933897 cites W3128040297 @default.
- W4220933897 cites W3134157433 @default.
- W4220933897 cites W3143666723 @default.
- W4220933897 cites W3159336508 @default.
- W4220933897 cites W3161511284 @default.
- W4220933897 cites W3167899755 @default.
- W4220933897 cites W3180290398 @default.
- W4220933897 cites W3189229110 @default.
- W4220933897 cites W3201481311 @default.
- W4220933897 cites W3205497012 @default.
- W4220933897 cites W3206621042 @default.
- W4220933897 cites W3207499096 @default.
- W4220933897 cites W3208944826 @default.
- W4220933897 cites W4200093500 @default.
- W4220933897 cites W4205525789 @default.
- W4220933897 cites W4210784463 @default.
- W4220933897 cites W4211123803 @default.
- W4220933897 cites W4213314719 @default.
- W4220933897 cites W4230175438 @default.
- W4220933897 cites W4231345156 @default.
- W4220933897 cites W4231759873 @default.
- W4220933897 cites W4242264495 @default.
- W4220933897 cites W4242983534 @default.
- W4220933897 cites W4250053626 @default.
- W4220933897 cites W4254364179 @default.
- W4220933897 cites W4255309630 @default.
- W4220933897 cites W4385643799 @default.
- W4220933897 doi "https://doi.org/10.1002/ange.202201436" @default.
- W4220933897 hasPublicationYear "2022" @default.
- W4220933897 type Work @default.
- W4220933897 citedByCount "1" @default.
- W4220933897 crossrefType "journal-article" @default.
- W4220933897 hasAuthorship W4220933897A5000952268 @default.
- W4220933897 hasAuthorship W4220933897A5002068991 @default.
- W4220933897 hasAuthorship W4220933897A5023229525 @default.
- W4220933897 hasAuthorship W4220933897A5023473958 @default.
- W4220933897 hasAuthorship W4220933897A5031547714 @default.
- W4220933897 hasAuthorship W4220933897A5087744964 @default.
- W4220933897 hasConcept C109214941 @default.
- W4220933897 hasConcept C121332964 @default.
- W4220933897 hasConcept C124668440 @default.