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- W4220935331 abstract "Abstract Herein, we describe a unique one‐carbon ring‐expansion strategy to access multi‐substituted 2‐indanones from benzocyclobutenones and styrene‐type olefins. The use of a cationic “ligandless” rhodium catalyst was the key for both high reactivity and selectivity towards the (4+1) product. Broad functional group tolerance, a good substrate scope, and scalability have been demonstrated. Computation studies reveal that the origin of the (4+1) selectivity is due to a facile β‐H elimination pathway that reduces the overall barrier of the turnover‐limiting C−C reductive elimination step." @default.
- W4220935331 created "2022-04-03" @default.
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- W4220935331 date "2022-03-30" @default.
- W4220935331 modified "2023-10-16" @default.
- W4220935331 title "Rhodium‐Catalyzed (4+1) Cycloaddition between Benzocyclobutenones and Styrene‐Type Alkenes" @default.
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- W4220935331 doi "https://doi.org/10.1002/ange.202202703" @default.
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