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- W4220940734 abstract "For decades, the all-nitrogen substance tetranitrogen, a promising candidate for eco-friendly use as an ultra-high energy density material, has been of intense interest. Still, its experimental stabilization has never been achieved under ambient conditions. Here, the all-nitrogen aromatic N42¯ was found to obtain extra stability in sufficiently high concentration of hydronium ions or ammonium ions, leading to a productive yielding of the ultra-high energy density material for space exploration, high-value defense, and civil applications. The reactivity of N42¯ in various acidity was found to be a competition between the aromaticity of N42¯ and its proton affinity. At sufficiently high acidity, N42¯ begins to resist acid − base neutralization by forming a N42¯···4H3O+ complex. The intermolecular hydrogen bonding assists in reducing the mutual repulsion of nitrogen lone pair electrons and enhance the aromaticity of N42¯. By thus, the firmness of N42¯ was reinforced by 200%, strongly implying a promising application of the current strategy to facilitate the synthesis of N42¯. The current strategy of acidic trapping is expected to apply to other all-nitrogen aromatic compounds." @default.
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- W4220940734 date "2022-06-01" @default.
- W4220940734 modified "2023-09-29" @default.
- W4220940734 title "Conferring all-nitrogen aromatics extra stability by acidic trapping" @default.
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- W4220940734 doi "https://doi.org/10.1016/j.molliq.2022.118939" @default.
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