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- W4220954423 endingPage "132972" @default.
- W4220954423 startingPage "132972" @default.
- W4220954423 abstract "Unsymmetrical aza[7]helicene is synthesized and its photophysical properties are studied. Its functionalization is carried out by Vilsmeier-Haack formylation, followed by its conversion to chiral amino derivative. The two formyl derivatives were characterized by single crystal X-ray diffraction analysis. The diastereomeric 2-aminomethyl aza[7]helicene was obtained in optically pure form, which shows high optical rotation values. Geometry optimization of aza[7]helicene was carried out using B3LYP/6–31G(d,p) level of theory and its HOMO-LUMO energy gap was calculated." @default.
- W4220954423 created "2022-04-03" @default.
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- W4220954423 date "2022-08-01" @default.
- W4220954423 modified "2023-10-03" @default.
- W4220954423 title "Synthesis and characterization of aza[7]helicenes" @default.
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- W4220954423 doi "https://doi.org/10.1016/j.molstruc.2022.132972" @default.
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