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- W4220979770 abstract "Synthetic approaches to bicyclo[4.2.0]octadiene natural products frequently employ the synthesis of linear tetraenes to initiate a biosynthetic 8π/6π-electrocyclization cascade. This work forges a functionalized bicyclo[4.2.0]octadiene in two steps from cyclooctatetraene. The versatility of this method is demonstrated through natural product synthesis, including the first total synthesis of kingianic acid A and formal syntheses of kingianins A, D, and F and cryptobeilic acid D ethyl ester. The unexpected formation of an E,E,Z,E-tetraene byproduct is rationalized through density functional theory modeling." @default.
- W4220979770 created "2022-04-03" @default.
- W4220979770 creator A5047504911 @default.
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- W4220979770 date "2022-03-16" @default.
- W4220979770 modified "2023-09-30" @default.
- W4220979770 title "Two Steps to Bicyclo[4.2.0]octadienes from Cyclooctatetraene: Total Synthesis of Kingianic Acid A" @default.
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- W4220979770 doi "https://doi.org/10.1021/acs.orglett.2c00325" @default.
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