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- W4220991736 abstract "This work reports a site-selective C-H borylation of pyridines at the ortho-position with pinacolborane enabled by an yttrocene catalyst. The reaction provides a new family of 2-pyridyl boronates with a broad substrate scope and high atom efficiency. The resultant boronates were able to undergo a variety of transformations, e.g., oxidation, Suzuki-Miyaura coupling, Chan-Lam amination and etherification. Catalytic intermediates, including ortho-C-H metalated and borylated complexes, were isolated from stoichiometric experiments and confirmed by single-crystal X-ray diffraction." @default.
- W4220991736 created "2022-04-03" @default.
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- W4220991736 date "2022-03-23" @default.
- W4220991736 modified "2023-09-27" @default.
- W4220991736 title "Yttrium‐Catalyzed <i>ortho</i>‐Selective C−H Borylation of Pyridines with Pinacolborane" @default.
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- W4220991736 doi "https://doi.org/10.1002/anie.202117750" @default.
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