FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4221006321> ?p ?o ?g. }

• W4221006321 endingPage "4862" @default.
• W4221006321 startingPage "4853" @default.
• W4221006321 abstract "Conducting polymers (CPs) find applications in energy conversion and storage, sensors, and biomedical technologies once processed into thin films. Hydrophobic CPs, like poly(3,4-ethylenedioxythiophene) (PEDOT), typically require surfactant additives, such as poly(styrenesulfonate) (PSS), to aid their aqueous processability as thin films. However, excess PSS diminishes CP electrochemical performance, biocompatibility, and device stability. Here, we report the electrosynthesis of PEDOT thin films at a polarized liquid|liquid interface, a method nonreliant on conductive solid substrates that produces free-standing, additive-free, biocompatible, easily transferrable, and scalable 2D PEDOT thin films of any shape or size in a single step at ambient conditions. Electrochemical control of thin film nucleation and growth at the polarized liquid|liquid interface allows control over the morphology, transitioning from 2D (flat on both sides with a thickness of <50 nm) to Janus 3D (with flat and rough sides, each showing distinct physical properties, and a thickness of >850 nm) films. The PEDOT thin films were p-doped (approaching the theoretical limit), showed high π-π conjugation, were processed directly as thin films without insulating PSS and were thus highly conductive without post-processing. This work demonstrates that interfacial electrosynthesis directly produces PEDOT thin films with distinctive molecular architectures inaccessible in bulk solution or at solid electrode-electrolyte interfaces and emergent properties that facilitate technological advances. In this regard, we demonstrate the PEDOT thin film's superior biocompatibility as scaffolds for cellular growth, opening immediate applications in organic electrochemical transistor (OECT) devices for monitoring cell behavior over extended time periods, bioscaffolds, and medical devices, without needing physiologically unstable and poorly biocompatible PSS." @default.
• W4221006321 created "2022-04-03" @default.
• W4221006321 creator A5005028325 @default.
• W4221006321 creator A5014703396 @default.
• W4221006321 creator A5031557929 @default.
• W4221006321 creator A5032790670 @default.
• W4221006321 creator A5040871669 @default.
• W4221006321 creator A5055015971 @default.
• W4221006321 creator A5060486643 @default.
• W4221006321 creator A5079062879 @default.
• W4221006321 creator A5088659906 @default.
• W4221006321 creator A5090569594 @default.
• W4221006321 date "2022-03-09" @default.
• W4221006321 modified "2023-10-15" @default.
• W4221006321 title "Electrosynthesis of Biocompatible Free-Standing PEDOT Thin Films at a Polarized Liquid|Liquid Interface" @default.
• W4221006321 cites W1966719633 @default.
• W4221006321 cites W1971004312 @default.
• W4221006321 cites W1975530670 @default.
• W4221006321 cites W1980434613 @default.
• W4221006321 cites W1988503356 @default.
• W4221006321 cites W1993162343 @default.
• W4221006321 cites W1993829091 @default.
• W4221006321 cites W2000060170 @default.
• W4221006321 cites W2009456380 @default.
• W4221006321 cites W2009801404 @default.
• W4221006321 cites W2023418515 @default.
• W4221006321 cites W2024161121 @default.
• W4221006321 cites W2032381973 @default.
• W4221006321 cites W2034734459 @default.
• W4221006321 cites W2035669105 @default.
• W4221006321 cites W2038321588 @default.
• W4221006321 cites W2039827529 @default.
• W4221006321 cites W2040260453 @default.
• W4221006321 cites W2046746391 @default.
• W4221006321 cites W2066839549 @default.
• W4221006321 cites W2071277647 @default.
• W4221006321 cites W2075447426 @default.
• W4221006321 cites W2078517430 @default.
• W4221006321 cites W2088506918 @default.
• W4221006321 cites W2093482917 @default.
• W4221006321 cites W2096480321 @default.
• W4221006321 cites W2098575085 @default.
• W4221006321 cites W2110858521 @default.
• W4221006321 cites W2148228860 @default.
• W4221006321 cites W2207639087 @default.
• W4221006321 cites W2214191075 @default.
• W4221006321 cites W2264322491 @default.
• W4221006321 cites W2284486709 @default.
• W4221006321 cites W2286207614 @default.
• W4221006321 cites W2293635208 @default.
• W4221006321 cites W2566193558 @default.
• W4221006321 cites W2588940762 @default.
• W4221006321 cites W2591726587 @default.
• W4221006321 cites W2766596384 @default.
• W4221006321 cites W2783763579 @default.
• W4221006321 cites W2791025612 @default.
• W4221006321 cites W2793539539 @default.
• W4221006321 cites W2793695449 @default.
• W4221006321 cites W2889868843 @default.
• W4221006321 cites W2893871680 @default.
• W4221006321 cites W2933420569 @default.
• W4221006321 cites W2943372450 @default.
• W4221006321 cites W2981523726 @default.
• W4221006321 cites W2981812809 @default.
• W4221006321 cites W2998552512 @default.
• W4221006321 cites W3002620370 @default.
• W4221006321 cites W3013619322 @default.
• W4221006321 cites W3019647360 @default.
• W4221006321 cites W3044345532 @default.
• W4221006321 cites W3100286355 @default.
• W4221006321 cites W3121083937 @default.
• W4221006321 doi "https://doi.org/10.1021/jacs.1c12373" @default.
• W4221006321 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35262332" @default.
• W4221006321 hasPublicationYear "2022" @default.
• W4221006321 type Work @default.
• W4221006321 citedByCount "26" @default.
• W4221006321 countsByYear W42210063212022 @default.
• W4221006321 countsByYear W42210063212023 @default.
• W4221006321 crossrefType "journal-article" @default.
• W4221006321 hasAuthorship W4221006321A5005028325 @default.
• W4221006321 hasAuthorship W4221006321A5014703396 @default.
• W4221006321 hasAuthorship W4221006321A5031557929 @default.
• W4221006321 hasAuthorship W4221006321A5032790670 @default.
• W4221006321 hasAuthorship W4221006321A5040871669 @default.
• W4221006321 hasAuthorship W4221006321A5055015971 @default.
• W4221006321 hasAuthorship W4221006321A5060486643 @default.
• W4221006321 hasAuthorship W4221006321A5079062879 @default.
• W4221006321 hasAuthorship W4221006321A5088659906 @default.
• W4221006321 hasAuthorship W4221006321A5090569594 @default.
• W4221006321 hasBestOaLocation W42210063211 @default.
• W4221006321 hasConcept C127413603 @default.
• W4221006321 hasConcept C133495861 @default.
• W4221006321 hasConcept C147789679 @default.
• W4221006321 hasConcept C159985019 @default.
• W4221006321 hasConcept C170029824 @default.
• W4221006321 hasConcept C171250308 @default.
• W4221006321 hasConcept C17525397 @default.
• W4221006321 hasConcept C185592680 @default.

• next