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- W4221008376 abstract "Treatment of an N-silyl-B-chloro-aminoborane with substoichio-metric quantities of Me3SiOTf afforded B-N coupling, whereas activation with 5 mol% of Ag[Al{OC(CF3)3}4] led to Cl/Me exchange between the boron and the silicon center. Combined experimental and computational studies of the latter process support a chain reaction that is initiated by nucleation-limited chloride abstraction." @default.
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- W4221008376 date "2022-01-01" @default.
- W4221008376 modified "2023-10-15" @default.
- W4221008376 title "Electrophilic activation of difunctional aminoboranes: B–N coupling <i>versus</i> intramolecular Cl/Me exchange" @default.
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- W4221008376 doi "https://doi.org/10.1039/d2cc00976e" @default.
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