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- W4221010209 abstract "An investigation of ferric ion complexing has been conducted in synthetic media and seawater at 25°C. In a potentiometric study, formation constants were determined for the species FeCl2+, FeCl2+, Fe(OH)2+ and Fe(OH)2+ at an ionic strength of 0.68 m. Formation constants for the ferric chloride complexes were determined as ClB1 = 2.76 and ClB2 = 0.44. In a study of the reaction Fe3+ + n H2O ⇌ Fe(OH)n(3-n)+ + n H+ in NaClO4, NaNO3 and NaCl the formation constants *B1 and *B2 were shown to be relatively independent of medium when the effects of nitrate and chloride complexing were accounted for. The average values obtained for these constants are *B1 = 1.93 x 10-3 and *B2 = 8.6 x 10-8. Reasonable agreement with these values was obtained when these constants were determined directly in seawater by accounting for the effects of chloride, fluoride and sulfate complexing." @default.
- W4221010209 created "2022-04-03" @default.
- W4221010209 creator A5086795617 @default.
- W4221010209 date "2022-03-11" @default.
- W4221010209 modified "2023-10-14" @default.
- W4221010209 title "Iron Speciation and Solubility in Sea Water" @default.
- W4221010209 doi "https://doi.org/10.23860/diss-byrne-robert-1974" @default.
- W4221010209 hasPublicationYear "2022" @default.
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