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- W4221014189 abstract "Water structure at the hydrophobic/water interface is key towards understanding hydrophobicity at the molecular level. Herein, we characterize the hydrogen bonding network of interfacial water next to sub-micron sized hydrophobic droplets dispersed in water using isotopic dilution vibrational sum frequency scattering (SFS) spectroscopy. The relative intensity of different modes, the frequency shift of the uncoupled O-D spectrum and a low frequency shoulder (2395 cm-1) reveal that water forms an overall stronger hydrogen bonding network next to hydrophobic droplets compared to bulk water and the air/water interface. Roughly half of the spectral width of the oil droplet SFS spectrum is determined by inter- and intramolecular coupling of water molecules. Isotopic dilution also revealed a broad distribution (~2640 – 2750 cm-1) of non-hydrogen bonded O-D modes that were red-shifted and broadened compared to similar species observed previously at the air/water interface. This band confirms the presence of charge transfer between water and oil." @default.
- W4221014189 created "2022-04-03" @default.
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- W4221014189 date "2022-03-14" @default.
- W4221014189 modified "2023-10-03" @default.
- W4221014189 title "Water Structure at the Hydrophobic Droplet Surface Revealed by Vibrational Sum Frequency Scattering using Isotopic Dilution" @default.
- W4221014189 doi "https://doi.org/10.26434/chemrxiv-2022-cpfwx" @default.
- W4221014189 hasPublicationYear "2022" @default.
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