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- W4221032793 abstract "The use of single-crystal substrates as templates for the epitaxial growth of single-crystal overlayers has been a primary principle of materials epitaxy for more than 70 years. Here we report our finding that, though counterintuitive, single-crystal 2D materials can be epitaxially grown on twinned crystals. By establishing a geometric principle to describe 2D materials alignment on high-index surfaces, we show that 2D material islands grown on the two sides of a twin boundary can be well aligned. To validate this prediction, wafer-scale Cu foils with abundant twin boundaries were synthesized, and on the surfaces of these polycrystalline Cu foils, we have successfully grown wafer-scale single-crystal graphene and hexagonal boron nitride films. In addition, to greatly increasing the availability of large area high-quality 2D single crystals, our discovery also extends the fundamental understanding of materials epitaxy." @default.
- W4221032793 created "2022-04-03" @default.
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- W4221032793 date "2022-04-01" @default.
- W4221032793 modified "2023-10-18" @default.
- W4221032793 title "Single-crystal two-dimensional material epitaxy on tailored non-single-crystal substrates" @default.
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- W4221032793 doi "https://doi.org/10.1038/s41467-022-29451-w" @default.
- W4221032793 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35365650" @default.
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