Matches in SemOpenAlex for { <https://semopenalex.org/work/W4221034733> ?p ?o ?g. }
- W4221034733 endingPage "112257" @default.
- W4221034733 startingPage "112257" @default.
- W4221034733 abstract "We present a simple catalyst preparation route, that is spinel-structured CoCrOx (1:2) loaded on N-doped carbon (CoCrOx (1:2)-CN). The as-synthesized CoCrOx (1:2)-CN catalyst promoted catalytic hydrogen transfer (CTH) of cinnamaldehyde (CMA), affording cinnamyl alcohol (CMO) yield as high as 95.3% under mild reaction conditions. There are several reasons for the high yield of CMA: (a) Through interfacial electron migration and N-doped carbon, the acidity and basicity of mesoporous CoCrOx (1:2)-CN catalyst were enhanced, thereby achieving optimal acid-base synergy. (b) Kinetic studies indicated that spinel-structure and N-doped carbon could increase the reaction rate and achieve a low activation energy (69.2 kJ/mol). (c) DFT calculations revealed that both pyridyl-N and pyrrolyl-N doping lowered the energy barrier for adsorption and desorption of reactants resulting in improved catalytic activity. In addition, the CoCrOx (1:2)-CN catalyst showed good reusability." @default.
- W4221034733 created "2022-04-03" @default.
- W4221034733 creator A5002661071 @default.
- W4221034733 creator A5019577856 @default.
- W4221034733 creator A5043416914 @default.
- W4221034733 creator A5067808070 @default.
- W4221034733 creator A5076118607 @default.
- W4221034733 creator A5079768458 @default.
- W4221034733 creator A5079916644 @default.
- W4221034733 date "2022-05-01" @default.
- W4221034733 modified "2023-10-16" @default.
- W4221034733 title "Co-Cr composite oxides efficiently catalyzed transfer hydrogenation of α, β-unsaturated aldehydes via N-doped carbon and interfacial electron migration" @default.
- W4221034733 cites W1979523591 @default.
- W4221034733 cites W1983669046 @default.
- W4221034733 cites W2015840254 @default.
- W4221034733 cites W2026399568 @default.
- W4221034733 cites W2029433003 @default.
- W4221034733 cites W2035261548 @default.
- W4221034733 cites W2039922946 @default.
- W4221034733 cites W2056208633 @default.
- W4221034733 cites W2081180002 @default.
- W4221034733 cites W2081248537 @default.
- W4221034733 cites W2084913979 @default.
- W4221034733 cites W2085020302 @default.
- W4221034733 cites W2088565063 @default.
- W4221034733 cites W2123661814 @default.
- W4221034733 cites W2159163776 @default.
- W4221034733 cites W2159911834 @default.
- W4221034733 cites W2178879844 @default.
- W4221034733 cites W2192588679 @default.
- W4221034733 cites W2298482557 @default.
- W4221034733 cites W2301770936 @default.
- W4221034733 cites W2313993625 @default.
- W4221034733 cites W2325707135 @default.
- W4221034733 cites W2419015170 @default.
- W4221034733 cites W2436872840 @default.
- W4221034733 cites W2508642938 @default.
- W4221034733 cites W2523003532 @default.
- W4221034733 cites W2528956049 @default.
- W4221034733 cites W2531064296 @default.
- W4221034733 cites W2561702792 @default.
- W4221034733 cites W2564367607 @default.
- W4221034733 cites W2580793213 @default.
- W4221034733 cites W2591921452 @default.
- W4221034733 cites W2610808410 @default.
- W4221034733 cites W2611657352 @default.
- W4221034733 cites W2782445384 @default.
- W4221034733 cites W2789344656 @default.
- W4221034733 cites W2887208850 @default.
- W4221034733 cites W2905285650 @default.
- W4221034733 cites W2913771539 @default.
- W4221034733 cites W2928153393 @default.
- W4221034733 cites W3157869857 @default.
- W4221034733 cites W622234173 @default.
- W4221034733 doi "https://doi.org/10.1016/j.mcat.2022.112257" @default.
- W4221034733 hasPublicationYear "2022" @default.
- W4221034733 type Work @default.
- W4221034733 citedByCount "1" @default.
- W4221034733 countsByYear W42210347332022 @default.
- W4221034733 crossrefType "journal-article" @default.
- W4221034733 hasAuthorship W4221034733A5002661071 @default.
- W4221034733 hasAuthorship W4221034733A5019577856 @default.
- W4221034733 hasAuthorship W4221034733A5043416914 @default.
- W4221034733 hasAuthorship W4221034733A5067808070 @default.
- W4221034733 hasAuthorship W4221034733A5076118607 @default.
- W4221034733 hasAuthorship W4221034733A5079768458 @default.
- W4221034733 hasAuthorship W4221034733A5079916644 @default.
- W4221034733 hasConcept C104779481 @default.
- W4221034733 hasConcept C123669783 @default.
- W4221034733 hasConcept C134121241 @default.
- W4221034733 hasConcept C140205800 @default.
- W4221034733 hasConcept C150394285 @default.
- W4221034733 hasConcept C159985019 @default.
- W4221034733 hasConcept C161790260 @default.
- W4221034733 hasConcept C162711632 @default.
- W4221034733 hasConcept C178790620 @default.
- W4221034733 hasConcept C179104552 @default.
- W4221034733 hasConcept C185592680 @default.
- W4221034733 hasConcept C191897082 @default.
- W4221034733 hasConcept C192562407 @default.
- W4221034733 hasConcept C2776230739 @default.
- W4221034733 hasConcept C2777435628 @default.
- W4221034733 hasConcept C2780440420 @default.
- W4221034733 hasConcept C82776694 @default.
- W4221034733 hasConceptScore W4221034733C104779481 @default.
- W4221034733 hasConceptScore W4221034733C123669783 @default.
- W4221034733 hasConceptScore W4221034733C134121241 @default.
- W4221034733 hasConceptScore W4221034733C140205800 @default.
- W4221034733 hasConceptScore W4221034733C150394285 @default.
- W4221034733 hasConceptScore W4221034733C159985019 @default.
- W4221034733 hasConceptScore W4221034733C161790260 @default.
- W4221034733 hasConceptScore W4221034733C162711632 @default.
- W4221034733 hasConceptScore W4221034733C178790620 @default.
- W4221034733 hasConceptScore W4221034733C179104552 @default.
- W4221034733 hasConceptScore W4221034733C185592680 @default.
- W4221034733 hasConceptScore W4221034733C191897082 @default.
- W4221034733 hasConceptScore W4221034733C192562407 @default.
- W4221034733 hasConceptScore W4221034733C2776230739 @default.