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- W4221042034 abstract "Callilongisin B, isolated in 2012, is a 3,4-seco-abietane-type diterpenoid having four stereocenters, whereas callilongisin C has an aromatic ring structure. Total syntheses of ent-callilongisins B and C were accomplished via a common intermediate in 19 steps and 22 steps, respectively. The key feature for the synthesis of ent-callilongisin B is an oxidative dearomatization accompanied by δ-lactonization and the synthetic method of ent-callilongisin C includes Suzuki coupling for installation of a carbon unit and Mukaiyama hydration." @default.
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- W4221042034 date "2022-04-01" @default.
- W4221042034 modified "2023-10-16" @default.
- W4221042034 title "Asymmetric syntheses of ent-callilongisins B and C" @default.
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- W4221042034 doi "https://doi.org/10.1016/j.tet.2022.132712" @default.
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