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- W4221100331 abstract "The conductive network within a lithium-ion battery electrode is mainly influenced by the process parameters chosen for the dry mixing and wet dispersing step during the production of a coatable electrode slurry, consisting of well-defined components. This conductive network, which results from the electrode's microstructure, plays a major role for the resulting battery cell performance, especially for high performance and power applications. Notable differences can be observed in the subsequently manufactured electrodes due to process-related modifications in the carbon black agglomerate size; mechanical, electrical, and, thus, electrochemical properties are significantly changing with the process parameters set. To allow for a direct correlation of these properties with the electrode structure, a characteristic parameter to describe the carbon black structure in electrode coatings is developed. Based on mercury intrusion measurements, the internal porosity of carbon black particles was determined as a characteristic parameter for the conductive microstructure. For a wide variety of lithium-ion battery cathode samples, the carbon black porosity can be well related to important electrode properties. This underscores the relevance of this carbon black-based microstructure parameter for a knowledge-based process and product optimization." @default.
- W4221100331 created "2022-04-03" @default.
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- W4221100331 date "2022-05-01" @default.
- W4221100331 modified "2023-10-17" @default.
- W4221100331 title "Inner carbon black porosity as characteristic parameter for the microstructure of lithium-ion electrodes and its effect on physical and electrochemical properties" @default.
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- W4221100331 doi "https://doi.org/10.1016/j.jpowsour.2022.231259" @default.
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