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- W4223456618 abstract "In this work, the advantages of in situ loading, heterojunction construction, and facet regulation were integrated based on the poly-facet-exposed BiOCl single crystal, and a facet-oriented supported heterojunction of Cu2O and BiOCl was fabricated (Cu2O@BiOCl[100]). The photocatalytic nitrogen reduction reaction (pNRR) activity of Cu2O@BiOCl[100] was as high as 181.9 μmol·g-1·h-1, which is 4.09, 7.13, and 1.83 times that of Cu2O, BiOCl, and Cu2O@BiOCl-ran (Cu2O randomly supported on BiOCl). Combined with the results of the photodeposition experiment, X-ray photoelectron spectroscopy characterization, and DFT calculation, the mechanism of Cu2O@BiOCl[100] for pNRR was discussed. When Cu2O directionally loaded on the [100] facet of BiOCl, electrons generated by Cu2O will be transmitted to the [100] facet of BiOCl through Z-scheme electron transmission. Due to the directional separation characteristics of charge in BiOCl, the electrons transmitted from Cu2O are enriched on the [001] facet of BiOCl, which will together with the original electrons generated by pristine BiOCl act on pNRR, thus greatly improving the activity of photocatalytic ammonia synthesis. Thus, a new construction scheme of biphasic semiconductor heterojunction was proposed, which provides a reference research idea for designing and synthesizing high-performance photocatalysts for nitrogen reduction." @default.
- W4223456618 created "2022-04-14" @default.
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- W4223456618 date "2022-04-12" @default.
- W4223456618 modified "2023-10-17" @default.
- W4223456618 title "High-Efficiency Photocatalytic Ammonia Synthesis by Facet Orientation-Supported Heterojunction Cu<sub>2</sub>O@BiOCl[100] Boosted by Double Built-In Electric Fields" @default.
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- W4223456618 doi "https://doi.org/10.1021/acs.inorgchem.2c00058" @default.
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