Matches in SemOpenAlex for { <https://semopenalex.org/work/W4223537674> ?p ?o ?g. }
- W4223537674 endingPage "120557" @default.
- W4223537674 startingPage "120557" @default.
- W4223537674 abstract "Glassy perfluoropolymers offer a remarkable resistance towards many species that can alter the separation performance of conventional polymeric membranes. In this study, the performance of Cytop® and CyclAFlor™ random copolymers of perfluoro(butenyl vinyl ether) (PBVE) and perfluoro(2,2-dimethyl-1,3-dioxole) (PDD) are studied for the first time for carbon dioxide capture in the presence of impurities that are common in raw natural gas. Water vapor sorption isotherms were S-shaped for both polymers, indicating the formation of water clusters. The water permeability decreased with vapor activity in both perfluoropolymers as the formation of these clusters decreased water diffusivity. The presence of the water clusters, however, had no impact on the performance of Cytop® and poly(50%PBVE-co-50%PDD) for CO2/CH4 separation. Typical concave sorption isotherms were obtained for toluene and xylene in poly(50%PBVE-co-50%PDD), while convex isotherms were observed in Cytop®. It was speculated that this change in isotherm shape may have been due to the small number of larger free volume elements within Cytop®, as observed in x-ray diffraction analysis. Neither toluene nor xylene had a significant impact on CO2 and CH4 permeabilities in Cytop®, while a gradual decrease in both permeabilities was noted for poly(50%PBVE-co-50%PDD) as the vapor activity increased, due to either competitive sorption or pore blocking. Finally, liquid glycol carryover caused no change on the performance of Cytop® membranes, while a slight drop in the CO2/CH4 separation factor for poly(50%PBVE-co-50%PDD) was observed." @default.
- W4223537674 created "2022-04-15" @default.
- W4223537674 creator A5003554962 @default.
- W4223537674 creator A5004500886 @default.
- W4223537674 creator A5034593811 @default.
- W4223537674 creator A5048935819 @default.
- W4223537674 date "2022-07-01" @default.
- W4223537674 modified "2023-10-17" @default.
- W4223537674 title "The impact of water, BTEX compounds and ethylene glycol on the performance of perfluoro(butenyl vinyl ether) based membranes for CO2 capture from natural gas" @default.
- W4223537674 cites W1505577598 @default.
- W4223537674 cites W1969059188 @default.
- W4223537674 cites W1975494359 @default.
- W4223537674 cites W1979365279 @default.
- W4223537674 cites W1982068477 @default.
- W4223537674 cites W1992300523 @default.
- W4223537674 cites W1998630020 @default.
- W4223537674 cites W1999714621 @default.
- W4223537674 cites W2003717719 @default.
- W4223537674 cites W2009432927 @default.
- W4223537674 cites W2012771196 @default.
- W4223537674 cites W2020505679 @default.
- W4223537674 cites W2035206161 @default.
- W4223537674 cites W2038934381 @default.
- W4223537674 cites W2039232312 @default.
- W4223537674 cites W2039742945 @default.
- W4223537674 cites W2042383152 @default.
- W4223537674 cites W2042699930 @default.
- W4223537674 cites W2043866671 @default.
- W4223537674 cites W2044087202 @default.
- W4223537674 cites W2047335111 @default.
- W4223537674 cites W2052925490 @default.
- W4223537674 cites W2061721687 @default.
- W4223537674 cites W2068948486 @default.
- W4223537674 cites W2073662917 @default.
- W4223537674 cites W2076902316 @default.
- W4223537674 cites W2116713892 @default.
- W4223537674 cites W2166340487 @default.
- W4223537674 cites W2312817826 @default.
- W4223537674 cites W2344184740 @default.
- W4223537674 cites W2472422608 @default.
- W4223537674 cites W2588947831 @default.
- W4223537674 cites W2621530674 @default.
- W4223537674 cites W2622652490 @default.
- W4223537674 cites W2764184599 @default.
- W4223537674 cites W2772805581 @default.
- W4223537674 cites W2790519278 @default.
- W4223537674 cites W2791345939 @default.
- W4223537674 cites W2794209960 @default.
- W4223537674 cites W2883532533 @default.
- W4223537674 cites W2997380729 @default.
- W4223537674 cites W3160770442 @default.
- W4223537674 cites W4301955086 @default.
- W4223537674 doi "https://doi.org/10.1016/j.memsci.2022.120557" @default.
- W4223537674 hasPublicationYear "2022" @default.
- W4223537674 type Work @default.
- W4223537674 citedByCount "4" @default.
- W4223537674 countsByYear W42235376742022 @default.
- W4223537674 countsByYear W42235376742023 @default.
- W4223537674 crossrefType "journal-article" @default.
- W4223537674 hasAuthorship W4223537674A5003554962 @default.
- W4223537674 hasAuthorship W4223537674A5004500886 @default.
- W4223537674 hasAuthorship W4223537674A5034593811 @default.
- W4223537674 hasAuthorship W4223537674A5048935819 @default.
- W4223537674 hasConcept C127413603 @default.
- W4223537674 hasConcept C147534773 @default.
- W4223537674 hasConcept C150394285 @default.
- W4223537674 hasConcept C178790620 @default.
- W4223537674 hasConcept C185592680 @default.
- W4223537674 hasConcept C188027245 @default.
- W4223537674 hasConcept C2777516009 @default.
- W4223537674 hasConcept C2778142098 @default.
- W4223537674 hasConcept C2778519274 @default.
- W4223537674 hasConcept C2779896714 @default.
- W4223537674 hasConcept C2780407432 @default.
- W4223537674 hasConcept C41625074 @default.
- W4223537674 hasConcept C42360764 @default.
- W4223537674 hasConcept C521977710 @default.
- W4223537674 hasConcept C55493867 @default.
- W4223537674 hasConcept C58445606 @default.
- W4223537674 hasConceptScore W4223537674C127413603 @default.
- W4223537674 hasConceptScore W4223537674C147534773 @default.
- W4223537674 hasConceptScore W4223537674C150394285 @default.
- W4223537674 hasConceptScore W4223537674C178790620 @default.
- W4223537674 hasConceptScore W4223537674C185592680 @default.
- W4223537674 hasConceptScore W4223537674C188027245 @default.
- W4223537674 hasConceptScore W4223537674C2777516009 @default.
- W4223537674 hasConceptScore W4223537674C2778142098 @default.
- W4223537674 hasConceptScore W4223537674C2778519274 @default.
- W4223537674 hasConceptScore W4223537674C2779896714 @default.
- W4223537674 hasConceptScore W4223537674C2780407432 @default.
- W4223537674 hasConceptScore W4223537674C41625074 @default.
- W4223537674 hasConceptScore W4223537674C42360764 @default.
- W4223537674 hasConceptScore W4223537674C521977710 @default.
- W4223537674 hasConceptScore W4223537674C55493867 @default.
- W4223537674 hasConceptScore W4223537674C58445606 @default.
- W4223537674 hasFunder F4320320974 @default.
- W4223537674 hasFunder F4320326056 @default.
- W4223537674 hasLocation W42235376741 @default.