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- W4223538939 abstract "Formal intramolecular 1,3-OH migration of α-imino carbene was achieved producing a unique zwitterion, and the subsequent selective annulation afforded α-amino cyclobutanone. Features such as readily available substrates, mild reaction conditions, a time-saving procedure, excellent functional group compatibility, and valuable transformations of the products qualified this unique protocol as an efficient tool for the synthesis of strained cyclic compounds. Density functional theory calculations were in good agreement with experimental observations, and a plausible mechanism is presented." @default.
- W4223538939 created "2022-04-15" @default.
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- W4223538939 date "2022-04-13" @default.
- W4223538939 modified "2023-10-18" @default.
- W4223538939 title "Synthesis of α-Amino Cyclobutanones via Formal 1,3-Hydroxy Migration Triggered by Formation of α-Imino Rhodium Carbene" @default.
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- W4223538939 doi "https://doi.org/10.1021/acs.orglett.2c01029" @default.
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