Matches in SemOpenAlex for { <https://semopenalex.org/work/W4223552405> ?p ?o ?g. }
- W4223552405 endingPage "6717" @default.
- W4223552405 startingPage "6707" @default.
- W4223552405 abstract "While the interest in single-molecule magnets (SMMs) lies in their potential applications in information storage and quantum computing, the switching of their slow magnetic relaxation associated with dynamic crystal-to-crystal transformation is insufficiently exploited. Herein, three pentagonal-bipyramidal (PBP) Dy(III) complexes, [Dy(Bcpen)(Cl)3] (1), [Dy(Bcpen)(OPhCl2NO2)3] (2) and [Dy(Bcpen)(OPhCl2NO2)3]·0.5CH3CN (2·CH3CN), are successfully assembled, and structurally and magnetically studied (Bcpen = N,N-bis(4-chloro-2-methylenepyridinyl) ethylenediamine and Cl2NO2PhOH = 2,6-dichloro-4-nitrophenol). The molecular characteristics and magnetic properties of complexes 2 and 2·CH3CN, constructed with the motivation of modulating a magnetic switch by external stimuli, are systematically explored. Dramatically, 2 and 2·CH3CN can mutually transform through reversible single-crystal-to-single-crystal (SCSC) conversion associated with the capture and release of guest CH3CN molecules, resulting in an infrequent on/off switching of PBP Dy(III) molecule-based magnets. Further measurements on the desolvated and resolvated samples, complexes 2-re and 2·CH3CN-re, confirm the fascinating transformation processes. The magneto-structural relationship has been rationally investigated and discussed with ab initio calculations as well." @default.
- W4223552405 created "2022-04-15" @default.
- W4223552405 creator A5000391502 @default.
- W4223552405 creator A5017584765 @default.
- W4223552405 creator A5021232406 @default.
- W4223552405 creator A5025389683 @default.
- W4223552405 creator A5042169456 @default.
- W4223552405 creator A5045307555 @default.
- W4223552405 creator A5062545097 @default.
- W4223552405 creator A5090844755 @default.
- W4223552405 date "2022-01-01" @default.
- W4223552405 modified "2023-10-18" @default.
- W4223552405 title "Reversible on–off switching of Dy(<scp>iii</scp>) single-molecule magnets <i>via</i> single-crystal-to-single-crystal transformation" @default.
- W4223552405 cites W1964488262 @default.
- W4223552405 cites W1969360633 @default.
- W4223552405 cites W1970881901 @default.
- W4223552405 cites W1970980886 @default.
- W4223552405 cites W1975434096 @default.
- W4223552405 cites W1985261148 @default.
- W4223552405 cites W1985741378 @default.
- W4223552405 cites W1986056398 @default.
- W4223552405 cites W2003608478 @default.
- W4223552405 cites W2018142068 @default.
- W4223552405 cites W2025508459 @default.
- W4223552405 cites W2026039351 @default.
- W4223552405 cites W2040593414 @default.
- W4223552405 cites W2054125484 @default.
- W4223552405 cites W2059205366 @default.
- W4223552405 cites W2075441846 @default.
- W4223552405 cites W2088631981 @default.
- W4223552405 cites W2097764239 @default.
- W4223552405 cites W2106989305 @default.
- W4223552405 cites W2110093832 @default.
- W4223552405 cites W2120586601 @default.
- W4223552405 cites W2152464446 @default.
- W4223552405 cites W2180053483 @default.
- W4223552405 cites W2226549565 @default.
- W4223552405 cites W2262205891 @default.
- W4223552405 cites W2290924027 @default.
- W4223552405 cites W2329653445 @default.
- W4223552405 cites W2332200090 @default.
- W4223552405 cites W2332402427 @default.
- W4223552405 cites W2333542309 @default.
- W4223552405 cites W2337775623 @default.
- W4223552405 cites W2461115542 @default.
- W4223552405 cites W2470375687 @default.
- W4223552405 cites W2535190622 @default.
- W4223552405 cites W2549302171 @default.
- W4223552405 cites W2567578746 @default.
- W4223552405 cites W2582454932 @default.
- W4223552405 cites W2594482283 @default.
- W4223552405 cites W2621844366 @default.
- W4223552405 cites W2746094390 @default.
- W4223552405 cites W2749576414 @default.
- W4223552405 cites W2765778691 @default.
- W4223552405 cites W2768547812 @default.
- W4223552405 cites W2774308797 @default.
- W4223552405 cites W2789950573 @default.
- W4223552405 cites W2791976090 @default.
- W4223552405 cites W2802889601 @default.
- W4223552405 cites W2808565924 @default.
- W4223552405 cites W2882604366 @default.
- W4223552405 cites W2887125060 @default.
- W4223552405 cites W2896379041 @default.
- W4223552405 cites W2896968078 @default.
- W4223552405 cites W2904476626 @default.
- W4223552405 cites W2963708117 @default.
- W4223552405 cites W2966110023 @default.
- W4223552405 cites W2978431136 @default.
- W4223552405 cites W2980891345 @default.
- W4223552405 cites W2991533823 @default.
- W4223552405 cites W2999224948 @default.
- W4223552405 cites W3003842012 @default.
- W4223552405 cites W3017201614 @default.
- W4223552405 cites W3045801594 @default.
- W4223552405 cites W3048744615 @default.
- W4223552405 cites W3090072163 @default.
- W4223552405 cites W3090730399 @default.
- W4223552405 cites W3119351632 @default.
- W4223552405 cites W4241748806 @default.
- W4223552405 cites W4242391388 @default.
- W4223552405 doi "https://doi.org/10.1039/d2dt00501h" @default.
- W4223552405 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35412548" @default.
- W4223552405 hasPublicationYear "2022" @default.
- W4223552405 type Work @default.
- W4223552405 citedByCount "2" @default.
- W4223552405 countsByYear W42235524052022 @default.
- W4223552405 countsByYear W42235524052023 @default.
- W4223552405 crossrefType "journal-article" @default.
- W4223552405 hasAuthorship W4223552405A5000391502 @default.
- W4223552405 hasAuthorship W4223552405A5017584765 @default.
- W4223552405 hasAuthorship W4223552405A5021232406 @default.
- W4223552405 hasAuthorship W4223552405A5025389683 @default.
- W4223552405 hasAuthorship W4223552405A5042169456 @default.
- W4223552405 hasAuthorship W4223552405A5045307555 @default.
- W4223552405 hasAuthorship W4223552405A5062545097 @default.
- W4223552405 hasAuthorship W4223552405A5090844755 @default.
- W4223552405 hasConcept C115260700 @default.