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- W4223609217 abstract "Catalytic fast pyrolysis of low sulfonated Kraft lignin was performed under different atmospheric environments such as N2, CH4, and the gas derived from CH4 decomposition (CH4-D). The use of Zn- or Mo-loaded HZSM-5 as catalyst led to a higher pyrolytic oil yield compared to parent HZSM-5 in CH4 and CH4-D atmospheres. The yields of benzene, toluene, and xylenes were increased by the synergistic effects from metal loading, higher H/Ceff ratio, higher acidity, and CH4 activation. The enhanced CH4 activation via metal loading resulted in higher methylation of alkyl moieties and 33% increase in the total yield of benzene, toluene, and xylenes in comparison to parent HZSM-5. A higher H/Ceff ratio of 6 via CH4 decomposition led to the formation of a hydro-pyrolysis environment. Moreover, the CH4-D environment showed H2/CH4 ratio of 0.36 in the product gas which warranted the presence of more H2 under the CH4-D pyrolysis environment." @default.
- W4223609217 created "2022-04-15" @default.
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- W4223609217 date "2022-06-01" @default.
- W4223609217 modified "2023-10-06" @default.
- W4223609217 title "Technical benefits of using methane as a pyrolysis medium for catalytic pyrolysis of Kraft lignin" @default.
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- W4223609217 doi "https://doi.org/10.1016/j.biortech.2022.127131" @default.
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