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• W4223905600 abstract "Because of the importance of fundamental research and practical applications of aggregation-induced emission (AIE), it has attracted the attention of a wide variety of researchers from different academic and technological backgrounds. Understanding the inherent mechanism of AIE can pave ways into the design of novel AIEgens and the development of their applications. In this chapter, we summarize our recent computational studies of the photophysical properties of representative AIEgens in various environments. We propose that the restriction of nonradiative decay channels in aggregate phase turns fluorescence on. The restriction of nonradiative decay channels occurs by the strong decoupling between electrons with various kinds of normal vibrational modes, such as rotating, stretching, bending, flipping, and twisting vibrations, and the demix among vibration modes. To validate the proposed AIE mechanism, we build the relationship between the theoretically available photophysical parameters and the experimentally visualizable signals. Furthermore, the molecular design strategy is proposed for AIEgen-based fluorescent probes to selectively target the cell membrane or mitochondria, and the theoretically designed AIE probes are confirmed by the cell imaging experiments." @default.
• W4223905600 created "2022-04-19" @default.
• W4223905600 creator A5039437624 @default.
• W4223905600 creator A5075443983 @default.
• W4223905600 date "2022-04-15" @default.
• W4223905600 modified "2023-10-17" @default.
• W4223905600 title "Understanding the AIE Mechanism at the Molecular Level" @default.
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• W4223905600 doi "https://doi.org/10.1002/9781119643098.ch2" @default.
• W4223905600 hasPublicationYear "2022" @default.
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