Matches in SemOpenAlex for { <https://semopenalex.org/work/W4223932050> ?p ?o ?g. }
Showing items 1 to 91 of
91
with 100 items per page.
- W4223932050 endingPage "128937" @default.
- W4223932050 startingPage "128937" @default.
- W4223932050 abstract "The impact of headgroup interactions in binary mixed monolayers comprised of fatty acids and alkyl amine-based surfactants has been investigated with a view towards understanding molecular pair formation at the air-water interface. Monolayers consisting of equimolar mixtures of cationic Stearyltrimethylammonium bromide with myristic acid (STAB/MA), and nominally neutral octadecyl amine with myristic acid (ODA/MA) were studied using a combination of Langmuir monolayer methods. Measurements support the formation of molecular pairs between STAB and MA in monolayers, which was not observed for the ODA/MA mixture. By studying the effect of subphase pH, measurements suggest hydrogen bonding between the headgroups and surrounding water significantly impacts film structure for the mixed systems. Notably, at pH 3.5, similarities in film morphology for the STAB/MA and the ODA/MA were observed, indicating that subphase pH can be used to enhance pair formation. This lower pH promoted the formation of phase-separated domains with LE and LC features and changed the kinetic stability of the monolayers. These works clarify the fundamental importance of headgroup interactions, hydrogen-bond formation and chemical structures in regulating intermolecular pair formation, an issue that has been largely unreported and underappreciated in the literature to date. This information can provide guidance on important intermolecular interaction considerations that must be taken into account for applied systems." @default.
- W4223932050 created "2022-04-19" @default.
- W4223932050 creator A5036253560 @default.
- W4223932050 creator A5082262888 @default.
- W4223932050 date "2022-07-01" @default.
- W4223932050 modified "2023-09-26" @default.
- W4223932050 title "Headgroup interaction effects in mixed fatty acid-alkyl amine monolayers" @default.
- W4223932050 cites W1963729026 @default.
- W4223932050 cites W1967433758 @default.
- W4223932050 cites W1973547981 @default.
- W4223932050 cites W1976501459 @default.
- W4223932050 cites W1980037098 @default.
- W4223932050 cites W2006179256 @default.
- W4223932050 cites W2016967573 @default.
- W4223932050 cites W2018869756 @default.
- W4223932050 cites W2038382075 @default.
- W4223932050 cites W2042965221 @default.
- W4223932050 cites W2047949686 @default.
- W4223932050 cites W2050695348 @default.
- W4223932050 cites W2051233833 @default.
- W4223932050 cites W2067121299 @default.
- W4223932050 cites W2083483279 @default.
- W4223932050 cites W2091823030 @default.
- W4223932050 cites W2093361390 @default.
- W4223932050 cites W2187245277 @default.
- W4223932050 cites W2329956138 @default.
- W4223932050 cites W2742984763 @default.
- W4223932050 cites W2941271528 @default.
- W4223932050 cites W3033840070 @default.
- W4223932050 doi "https://doi.org/10.1016/j.colsurfa.2022.128937" @default.
- W4223932050 hasPublicationYear "2022" @default.
- W4223932050 type Work @default.
- W4223932050 citedByCount "1" @default.
- W4223932050 countsByYear W42239320502023 @default.
- W4223932050 crossrefType "journal-article" @default.
- W4223932050 hasAuthorship W4223932050A5036253560 @default.
- W4223932050 hasAuthorship W4223932050A5082262888 @default.
- W4223932050 hasConcept C112887158 @default.
- W4223932050 hasConcept C115958267 @default.
- W4223932050 hasConcept C131779359 @default.
- W4223932050 hasConcept C166950319 @default.
- W4223932050 hasConcept C178790620 @default.
- W4223932050 hasConcept C184651966 @default.
- W4223932050 hasConcept C185592680 @default.
- W4223932050 hasConcept C2778483698 @default.
- W4223932050 hasConcept C2779936771 @default.
- W4223932050 hasConcept C2780263894 @default.
- W4223932050 hasConcept C32909587 @default.
- W4223932050 hasConcept C543025807 @default.
- W4223932050 hasConcept C55493867 @default.
- W4223932050 hasConcept C7070889 @default.
- W4223932050 hasConcept C71240020 @default.
- W4223932050 hasConcept C8010536 @default.
- W4223932050 hasConceptScore W4223932050C112887158 @default.
- W4223932050 hasConceptScore W4223932050C115958267 @default.
- W4223932050 hasConceptScore W4223932050C131779359 @default.
- W4223932050 hasConceptScore W4223932050C166950319 @default.
- W4223932050 hasConceptScore W4223932050C178790620 @default.
- W4223932050 hasConceptScore W4223932050C184651966 @default.
- W4223932050 hasConceptScore W4223932050C185592680 @default.
- W4223932050 hasConceptScore W4223932050C2778483698 @default.
- W4223932050 hasConceptScore W4223932050C2779936771 @default.
- W4223932050 hasConceptScore W4223932050C2780263894 @default.
- W4223932050 hasConceptScore W4223932050C32909587 @default.
- W4223932050 hasConceptScore W4223932050C543025807 @default.
- W4223932050 hasConceptScore W4223932050C55493867 @default.
- W4223932050 hasConceptScore W4223932050C7070889 @default.
- W4223932050 hasConceptScore W4223932050C71240020 @default.
- W4223932050 hasConceptScore W4223932050C8010536 @default.
- W4223932050 hasFunder F4320310865 @default.
- W4223932050 hasFunder F4320319952 @default.
- W4223932050 hasFunder F4320334593 @default.
- W4223932050 hasLocation W42239320501 @default.
- W4223932050 hasOpenAccess W4223932050 @default.
- W4223932050 hasPrimaryLocation W42239320501 @default.
- W4223932050 hasRelatedWork W2006252551 @default.
- W4223932050 hasRelatedWork W2012889060 @default.
- W4223932050 hasRelatedWork W2061552628 @default.
- W4223932050 hasRelatedWork W2079346183 @default.
- W4223932050 hasRelatedWork W2092833964 @default.
- W4223932050 hasRelatedWork W2094541203 @default.
- W4223932050 hasRelatedWork W2319441179 @default.
- W4223932050 hasRelatedWork W2501154560 @default.
- W4223932050 hasRelatedWork W2557642909 @default.
- W4223932050 hasRelatedWork W3164092408 @default.
- W4223932050 hasVolume "645" @default.
- W4223932050 isParatext "false" @default.
- W4223932050 isRetracted "false" @default.
- W4223932050 workType "article" @default.