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• W4223966163 endingPage "18599" @default.
• W4223966163 startingPage "18589" @default.
• W4223966163 abstract "Stable metal-organic frameworks containing periodically arranged nanosized pores and active Lewis acid-base active sites are considered as ideal candidates for efficient heterogeneous catalysis. Herein, the exquisite combination of [Y2(CO2)7(H2O)2] cluster (abbreviated as {Y2}) and multifunctional linker of 2,4,6-tri(2,4-dicarboxyphenyl)pyridine (H6TDP) led to a nanoporous framework of {[Y2(TDP)(H2O)2]·5H2O·4DMF}n (NUC-53, NUC = North University of China), which is a rarely reported binuclear three-dimensional (3D) framework with hierarchical tetragonal-microporous (0.78 nm) and octagonal-nanoporous (1.75 nm) channels. The inner walls of these channels are aligned by {Y2} clusters and plentifully coexisted Lewis acid-base sites of YIII ions and Npyridine atoms. Furthermore, NUC-53 has a quite large void volume of ∼65.2%, which is significantly higher than most documented 3D rare-earth-based MOFs. The performed catalytic experiments exhibited that activated NUC-53 showed a high catalytic activity on the cycloaddition reactions of CO2 with styrene oxide under mild conditions with excellent turnover number (TON: 1980) and turnover frequency (TOF: 495 h-1). Moreover, the deacetalization-Knoevenagel condensation reactions of benzaldehyde dimethyl acetal and malononitrile could be efficiently prompted by the heterogeneous catalyst of NUC-53. These findings not only pave the way for the construction of nanoporous MOF based on rare-earth clusters with a variety of catalytic activities but also provide some new insights into the catalytic mechanism." @default.
• W4223966163 created "2022-04-19" @default.
• W4223966163 creator A5055021669 @default.
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• W4223966163 date "2022-04-13" @default.
• W4223966163 modified "2023-10-18" @default.
• W4223966163 title "Nanoporous {Y₂}-Organic Frameworks for Excellent Catalytic Performance on the Cycloaddition Reaction of Epoxides with CO₂ and Deacetalization–Knoevenagel Condensation" @default.
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• W4223966163 doi "https://doi.org/10.1021/acsami.2c02929" @default.
• W4223966163 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35417126" @default.
• W4223966163 hasPublicationYear "2022" @default.
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