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- W4223979729 abstract "Bulk chemicals such as ethylene glycol (EG) can be industrially synthesized from either ethylene or syngas, but the latter undergoes a bottleneck reaction and requires high hydrogen pressures. We show that fullerene (exemplified by C60) can act as an electron buffer for a copper-silica catalyst (Cu/SiO2). Hydrogenation of dimethyl oxalate over a C60-Cu/SiO2 catalyst at ambient pressure and temperatures of 180° to 190°C had an EG yield of up to 98 ± 1%. In a kilogram-scale reaction, no deactivation of the catalyst was seen after 1000 hours. This mild route for the final step toward EG can be combined with the already-industrialized ambient reaction from syngas to the intermediate of dimethyl oxalate." @default.
- W4223979729 created "2022-04-19" @default.
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- W4223979729 date "2022-04-15" @default.
- W4223979729 modified "2023-10-06" @default.
- W4223979729 title "Ambient-pressure synthesis of ethylene glycol catalyzed by C <sub>60</sub> -buffered Cu/SiO <sub>2</sub>" @default.
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- W4223979729 doi "https://doi.org/10.1126/science.abm9257" @default.
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