Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224016883> ?p ?o ?g. }
- W4224016883 endingPage "9006" @default.
- W4224016883 startingPage "8999" @default.
- W4224016883 abstract "Furfuryl alcohol and thenyl alcohol contain a labile torsional chiral center, producing transiently chiral enantiomers interconverting in the nanosecond time-scale. We explored chiral molecular recognition using the weakly-bound intermolecular dimers of both alcohols, freezing stereomutation. Supersonic jet broadband microwave spectroscopy revealed homo and heterochiral diastereoisomers for each alcohol dimer and the structural characteristics of the clusters. All dimers are primarily stabilized by a moderately intense O-H⋯O hydrogen bond, but differ in the secondary interactions, which introduce additional hydrogen bonds either to the ring oxygen in furfuryl alcohol or to the π ring system in thenyl alcohol. Density-functional calculations (B2PLYP-D3(BJ)/def2-TZVP) show no clear preferences for a particular stereochemistry in the dimers, with relative energies of the order 1-2 kJ mol-1. The study suggests opportunities for the investigation of chiral recognition in molecules with torsional barriers in between transient and permanent interconversion regimes." @default.
- W4224016883 created "2022-04-19" @default.
- W4224016883 creator A5015084638 @default.
- W4224016883 creator A5021572015 @default.
- W4224016883 creator A5064729724 @default.
- W4224016883 creator A5074758294 @default.
- W4224016883 creator A5074818598 @default.
- W4224016883 creator A5089325372 @default.
- W4224016883 date "2022-01-01" @default.
- W4224016883 modified "2023-10-16" @default.
- W4224016883 title "Torsional chirality and molecular recognition: the homo and heterochiral dimers of thenyl and furfuryl alcohol" @default.
- W4224016883 cites W1966949133 @default.
- W4224016883 cites W1974590204 @default.
- W4224016883 cites W1983160087 @default.
- W4224016883 cites W1983899755 @default.
- W4224016883 cites W1986864663 @default.
- W4224016883 cites W1988091937 @default.
- W4224016883 cites W1989175214 @default.
- W4224016883 cites W1994125781 @default.
- W4224016883 cites W1995418060 @default.
- W4224016883 cites W1997532661 @default.
- W4224016883 cites W2002433816 @default.
- W4224016883 cites W2013825661 @default.
- W4224016883 cites W2034690089 @default.
- W4224016883 cites W2049215393 @default.
- W4224016883 cites W2050890227 @default.
- W4224016883 cites W2052362892 @default.
- W4224016883 cites W2054920099 @default.
- W4224016883 cites W2058115022 @default.
- W4224016883 cites W2058251027 @default.
- W4224016883 cites W2071579644 @default.
- W4224016883 cites W2079500784 @default.
- W4224016883 cites W2079957796 @default.
- W4224016883 cites W2088494529 @default.
- W4224016883 cites W2096747776 @default.
- W4224016883 cites W2102034252 @default.
- W4224016883 cites W2104919283 @default.
- W4224016883 cites W2125812064 @default.
- W4224016883 cites W2132109560 @default.
- W4224016883 cites W2143981217 @default.
- W4224016883 cites W2144239168 @default.
- W4224016883 cites W2148941593 @default.
- W4224016883 cites W2299015718 @default.
- W4224016883 cites W2335442430 @default.
- W4224016883 cites W2613386458 @default.
- W4224016883 cites W2624094034 @default.
- W4224016883 cites W2770562062 @default.
- W4224016883 cites W2794033465 @default.
- W4224016883 cites W2884762382 @default.
- W4224016883 cites W2893184896 @default.
- W4224016883 cites W2900311120 @default.
- W4224016883 cites W2914836107 @default.
- W4224016883 cites W3006234984 @default.
- W4224016883 cites W3025523052 @default.
- W4224016883 cites W3025931074 @default.
- W4224016883 cites W3122543629 @default.
- W4224016883 cites W3206245587 @default.
- W4224016883 cites W3210181987 @default.
- W4224016883 cites W4205995435 @default.
- W4224016883 doi "https://doi.org/10.1039/d2cp00479h" @default.
- W4224016883 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35380144" @default.
- W4224016883 hasPublicationYear "2022" @default.
- W4224016883 type Work @default.
- W4224016883 citedByCount "4" @default.
- W4224016883 countsByYear W42240168832022 @default.
- W4224016883 countsByYear W42240168832023 @default.
- W4224016883 crossrefType "journal-article" @default.
- W4224016883 hasAuthorship W4224016883A5015084638 @default.
- W4224016883 hasAuthorship W4224016883A5021572015 @default.
- W4224016883 hasAuthorship W4224016883A5064729724 @default.
- W4224016883 hasAuthorship W4224016883A5074758294 @default.
- W4224016883 hasAuthorship W4224016883A5074818598 @default.
- W4224016883 hasAuthorship W4224016883A5089325372 @default.
- W4224016883 hasConcept C112887158 @default.
- W4224016883 hasConcept C121332964 @default.
- W4224016883 hasConcept C124668440 @default.
- W4224016883 hasConcept C138716334 @default.
- W4224016883 hasConcept C147597530 @default.
- W4224016883 hasConcept C161790260 @default.
- W4224016883 hasConcept C166950319 @default.
- W4224016883 hasConcept C178790620 @default.
- W4224016883 hasConcept C185592680 @default.
- W4224016883 hasConcept C20621625 @default.
- W4224016883 hasConcept C2779546866 @default.
- W4224016883 hasConcept C2780378348 @default.
- W4224016883 hasConcept C2780526948 @default.
- W4224016883 hasConcept C2781066024 @default.
- W4224016883 hasConcept C32909587 @default.
- W4224016883 hasConcept C52703039 @default.
- W4224016883 hasConcept C62520636 @default.
- W4224016883 hasConcept C71240020 @default.
- W4224016883 hasConcept C75473681 @default.
- W4224016883 hasConcept C7602139 @default.
- W4224016883 hasConcept C8010536 @default.
- W4224016883 hasConceptScore W4224016883C112887158 @default.
- W4224016883 hasConceptScore W4224016883C121332964 @default.
- W4224016883 hasConceptScore W4224016883C124668440 @default.
- W4224016883 hasConceptScore W4224016883C138716334 @default.