FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224079476> ?p ?o ?g. }

• W4224079476 endingPage "10996" @default.
• W4224079476 startingPage "10989" @default.
• W4224079476 abstract "Three reactions of phosphanylphosphaalkene (1) with nucleophiles were performed to activate the diphosphorus monomer. We observed similar results in the reactions with MeLi and nBuLi, in which the P-P bond is cleavaged and triphosphorus systems [P(Me)2-CH(biph)-CH(biph)-P-(PtBu2)]- (1a'') and [P(nBu)2-CH(biph)-CH(biph)-P-(PtBu2)]- (1b''), respectively, are formed depending on the nucleophilic reagent (biph = biphenyl). In the case of tBuLi, the P-P bond remains intact; on the phosphorus atom, only one -tBu group is substituted, and as a result, [(biph)(H)C-P(tBu)-PtBu2]- (1c) is generated as a stable carbanion. We additionally investigated the effect of substitution in the phenyl ring in the course of these reactions by involving two other phosphanylphosphaalkenes (3 and 4). All initial reactions were conducted in tetrahydrofuran (THF) solution at ambient temperature." @default.
• W4224079476 created "2022-04-19" @default.
• W4224079476 creator A5024913036 @default.
• W4224079476 creator A5054574462 @default.
• W4224079476 creator A5079999572 @default.
• W4224079476 date "2022-01-01" @default.
• W4224079476 modified "2023-10-13" @default.
• W4224079476 title "Activation of the CP bond in phosphanylphosphaalkenes (CP–P bond system) in the reaction with nucleophilic reagents: MeLi, <i>n</i>BuLi and <i>t</i>BuLi" @default.
• W4224079476 cites W1974306731 @default.
• W4224079476 cites W1975535878 @default.
• W4224079476 cites W1983316362 @default.
• W4224079476 cites W1995925097 @default.
• W4224079476 cites W2000828198 @default.
• W4224079476 cites W2004529928 @default.
• W4224079476 cites W2022784733 @default.
• W4224079476 cites W2023630158 @default.
• W4224079476 cites W2039219023 @default.
• W4224079476 cites W2040026261 @default.
• W4224079476 cites W2041426400 @default.
• W4224079476 cites W2042005679 @default.
• W4224079476 cites W2042370999 @default.
• W4224079476 cites W2057228724 @default.
• W4224079476 cites W2060003242 @default.
• W4224079476 cites W2079735538 @default.
• W4224079476 cites W2090939454 @default.
• W4224079476 cites W2119239517 @default.
• W4224079476 cites W2128863896 @default.
• W4224079476 cites W2135731576 @default.
• W4224079476 cites W2142632588 @default.
• W4224079476 cites W2153554864 @default.
• W4224079476 cites W2154002553 @default.
• W4224079476 cites W2169508484 @default.
• W4224079476 cites W2334245800 @default.
• W4224079476 cites W2602978522 @default.
• W4224079476 cites W2614644787 @default.
• W4224079476 cites W2759871081 @default.
• W4224079476 cites W2789134065 @default.
• W4224079476 cites W2794663670 @default.
• W4224079476 cites W2809173866 @default.
• W4224079476 cites W2811164622 @default.
• W4224079476 cites W2944303098 @default.
• W4224079476 cites W2950567725 @default.
• W4224079476 cites W2963710979 @default.
• W4224079476 cites W2994396329 @default.
• W4224079476 cites W3007729030 @default.
• W4224079476 cites W3083414600 @default.
• W4224079476 cites W3117246235 @default.
• W4224079476 cites W3174393399 @default.
• W4224079476 cites W4231101723 @default.
• W4224079476 cites W4248068793 @default.
• W4224079476 doi "https://doi.org/10.1039/d1ra09215d" @default.
• W4224079476 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35425069" @default.
• W4224079476 hasPublicationYear "2022" @default.
• W4224079476 type Work @default.
• W4224079476 citedByCount "0" @default.
• W4224079476 crossrefType "journal-article" @default.
• W4224079476 hasAuthorship W4224079476A5024913036 @default.
• W4224079476 hasAuthorship W4224079476A5054574462 @default.
• W4224079476 hasAuthorship W4224079476A5079999572 @default.
• W4224079476 hasBestOaLocation W42240794761 @default.
• W4224079476 hasConcept C155647269 @default.
• W4224079476 hasConcept C161790260 @default.
• W4224079476 hasConcept C166940927 @default.
• W4224079476 hasConcept C178790620 @default.
• W4224079476 hasConcept C178907741 @default.
• W4224079476 hasConcept C185592680 @default.
• W4224079476 hasConcept C2776701986 @default.
• W4224079476 hasConcept C2780378348 @default.
• W4224079476 hasConcept C2780471494 @default.
• W4224079476 hasConcept C2780591471 @default.
• W4224079476 hasConcept C40875361 @default.
• W4224079476 hasConcept C521977710 @default.
• W4224079476 hasConcept C71240020 @default.
• W4224079476 hasConcept C82894169 @default.
• W4224079476 hasConceptScore W4224079476C155647269 @default.
• W4224079476 hasConceptScore W4224079476C161790260 @default.
• W4224079476 hasConceptScore W4224079476C166940927 @default.
• W4224079476 hasConceptScore W4224079476C178790620 @default.
• W4224079476 hasConceptScore W4224079476C178907741 @default.
• W4224079476 hasConceptScore W4224079476C185592680 @default.
• W4224079476 hasConceptScore W4224079476C2776701986 @default.
• W4224079476 hasConceptScore W4224079476C2780378348 @default.
• W4224079476 hasConceptScore W4224079476C2780471494 @default.
• W4224079476 hasConceptScore W4224079476C2780591471 @default.
• W4224079476 hasConceptScore W4224079476C40875361 @default.
• W4224079476 hasConceptScore W4224079476C521977710 @default.
• W4224079476 hasConceptScore W4224079476C71240020 @default.
• W4224079476 hasConceptScore W4224079476C82894169 @default.
• W4224079476 hasFunder F4320323690 @default.
• W4224079476 hasIssue "18" @default.
• W4224079476 hasLocation W42240794761 @default.
• W4224079476 hasLocation W42240794762 @default.
• W4224079476 hasLocation W42240794763 @default.
• W4224079476 hasOpenAccess W4224079476 @default.
• W4224079476 hasPrimaryLocation W42240794761 @default.
• W4224079476 hasRelatedWork W2021939235 @default.
• W4224079476 hasRelatedWork W2039597837 @default.
• W4224079476 hasRelatedWork W2162041534 @default.

• next