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- W4224095087 abstract "Abstract Two‐dimensional (2D) metal–organic frameworks (MOFs) used directly in supercapacitors have been a worldwide research interest for their potential high performance. Herein, one new 2D Co‐based MOF, [CoCo 0.5 Co 0.5 ( μ –ppa) 2 (H 2 O) 3 ] n , namely, ( BBU‐1 ), has been synthesized through solvothermal method with the ligand H 2 ppa (H 2 ppa = 3‐(pyrazin‐2‐ yl )‐1 H ‐pyrazole‐5‐carboxylic acid). Single X‐ray diffraction analysis shows that the BBU‐1 exhibits a (3, 4, 6‐ c )‐connected 2D structure bridged through the carboxylic group, with the topological point symbol of {3·4·5} 2 {3 2 ·4 2 ·5 2 ·6 2 ·7 4 ·8 2 ·9}{3 2 ·6 2 ·7 2 }. PXRD Rietveld refinement also has been employed to confirm the structure. The Co‐MOF electrode showed a high specific capacitance and a good cycling stability. Its maximum specific capacitance was 134.5 F g −1 at 3 mV s −1 , and the specific capacitance retention is about 91.3% after 1000 cycles at a current density of 2 A g −1 in the 2‐M KOH solution. These results show that the pristine 2D Co‐MOF is an excellent candidate of electrode active material for electrochemical energy storage." @default.
- W4224095087 created "2022-04-19" @default.
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- W4224095087 date "2022-04-06" @default.
- W4224095087 modified "2023-09-26" @default.
- W4224095087 title "Highly stable supercapacitive performance of a (3, 4, 6‐<i>c</i>)‐connected 2D Co‐MOF" @default.
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- W4224095087 doi "https://doi.org/10.1002/aoc.6684" @default.
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