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- W4224211316 abstract "We report the alternating copolymerization of caprolactone and epoxide through the in situ formation of pre-sequenced spiroorthoester monomer. The reaction is catalyzed by the temperature triggered, bifunctional cationic indium complex (±)-[(NNiOtBu)In(CH2SiMe3)][B(C6F5)4] (1). 1 can catalyze the coupling of epoxide and lactone to form spiroorthoester at 60 °C and its double ring-opening polymerization at 110 °C to form poly(ether-alt-ester). The post-polymerization modification and degradation of the poly(ether-alt-ester) are further investigated." @default.
- W4224211316 created "2022-04-26" @default.
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- W4224211316 date "2022-01-01" @default.
- W4224211316 modified "2023-10-06" @default.
- W4224211316 title "Temperature triggered alternating copolymerization of epoxides and lactones <i>via</i> pre-sequenced spiroorthoester intermediates" @default.
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- W4224211316 doi "https://doi.org/10.1039/d1sc06634j" @default.
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