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- W4224229157 abstract "The halogenation of the heterobimetallic triple-decker complexes [(Cp*Fe)(Cp‴Co)(µ,η 5 :η 4 -E 5 )] (E = P, As) shows that the reaction provides different products depending on the halogen and on the nature of the pnictogen used. I 2 and Br 2 lead to similar nortricylane-like derivatives with phosphorus and to homometallic triple-decker compounds with arsenic. The halogenation of the heterobimetallic triple-decker complexes [(Cp*Fe)(Cp‴Co)(µ,η 5 :η 4 -E 5 )] (E = P ( 1 ), As ( 6 ), Cp* = η 5 -C 5 Me 5 , Cp‴ = 1,2,4-tri( tert -butyl)cyclopentadienyl) was investigated. Compound 1 has been oxidised to the isostructural ionic compounds [(Cp*Fe)(Cp‴Co)(µ-PX)(µ,η 2 :η 1 :η 1 -P 4 X 4 )][Y] (X = I, Y = [I 3 ] ( 2 ), X = Br, Y = [FeBr 4 ] ( 3 )) and to the neutral species [(Cp*Fe)(Cp‴Co)(µ-PCl 2 )(µ,η 2 :η 1 :η 1 -P 4 Cl 4 )] ( 4 ) and [(Cp*Fe)(Cp‴Co)(µ-PCl 2 ) 2 (µ,η 1 :η 1 -P 2 Cl 3 )] ( 5 ). Compounds 2 , 3 and 4 possess a heterobimetallic nortricyclane-like FeCoP 5 core. The oxidation of the heavier homologue 6 with bromine and iodine afforded the homometallic complexes [(Cp‴Co) 2 (µ,η 4 :η 4 -As 4 X)][FeX 4 ] (X = I ( 7 ) and X = Br ( 9 )). With iodine as halogenating agent, the trinuclear monocation bearing an As 6 prism as ligand [(Cp*Fe)(Cp‴Co) 2 (µ 3 ,η 4 :η 4 :η 4 -As 6 )][FeI 4 ] ( 8 ) was additionally isolated. When PCl 5 was used as oxidizing agent, the initially folded As 5 ligand planarised resulting in the dicationic species [(Cp*Fe)(Cp‴Co)(µ,η 5 :η 5 -As 5 )][FeCl 4 ] 2 ( 10 )." @default.
- W4224229157 created "2022-04-26" @default.
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- W4224229157 date "2022-07-01" @default.
- W4224229157 modified "2023-09-27" @default.
- W4224229157 title "Halogenation of heterobimetallic triple-decker complexes containing an E5 middle deck (E = P, As)" @default.
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- W4224229157 doi "https://doi.org/10.1016/j.poly.2022.115854" @default.
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