FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224229722> ?p ?o ?g. }

• W4224229722 abstract "Abstract Four new M I /Cu II /Te IV /O phases were obtained under hydrothermal conditions or with water as a mineralizer, and their crystal structures determined by single‐crystal X‐ray diffraction. Li 2 Cu 2 Te 3 O 9 comprises trigonal‐pyramidal [TeO 3 ], distorted tetrahedral [LiO 4 ] and distorted square‐pyramidal [CuO 5 ] units, forming a framework penetrated by channels into which the electron lone pairs of the Te IV atoms are directed. Li 2 Cu 3 Te 4 O 12 contains isolated trigonal‐pyramidal [TeO 3 ] units, tetrahedral [LiO 4 ] groups forming [Li 2 O 6 ] dimers by sharing an edge, as well as square‐planar [CuO 4 ] and square‐pyramidal [CuO 5 ] units, forming [Cu 3 O 10 ] chains oriented parallel to [100]. These units also form a framework structure with channels where the electron lone pairs reside. Rb 2 Cu 3 Te 6 O 16 and Cs 2 Cu 3 Te 6 O 16 have isopointal crystal structures containing isolated [TeO 3 ] groups and [Te 4 O 10 ] chains oriented parallel to [010]. While in Rb 2 Cu 3 Te 6 O 16 both Cu sites are 4‐coordinate in form of nearly square‐planar [CuO 4 ] units, in Cs 2 Cu 3 Te 6 O 16 one Cu site has a fifth oxygen contact resulting in a distorted square‐pyramidal [CuO 5 ] polyhedron. Both crystal structures are made up from two alternating layer types stacked along [100]. The differences between Rb 2 Cu 3 Te 6 O 16 and Cs 2 Cu 3 Te 6 O 16 originate almost exclusively from the layer type consisting of the 5‐coordinate Cu site in Cs 2 Cu 3 Te 6 O 16 , while the other layer type shows almost no difference. A quantitative comparison between the two crystal structures is given." @default.
• W4224229722 created "2022-04-26" @default.
• W4224229722 creator A5032283210 @default.
• W4224229722 creator A5058070501 @default.
• W4224229722 date "2022-04-22" @default.
• W4224229722 modified "2023-10-16" @default.
• W4224229722 title "The alkali metal copper(II) oxidotellurates(IV) Li₂Cu₂Te₃O₉, Li₂Cu₃Te₄O₁₂, Rb₂Cu₃Te₆O₁₆ and Cs₂Cu₃Te₆O₁₆ – four new structure types" @default.
• W4224229722 cites W1802826053 @default.
• W4224229722 cites W1969360633 @default.
• W4224229722 cites W1981576154 @default.
• W4224229722 cites W1982590801 @default.
• W4224229722 cites W2023630158 @default.
• W4224229722 cites W2036127775 @default.
• W4224229722 cites W2048937028 @default.
• W4224229722 cites W2101547779 @default.
• W4224229722 cites W2101741054 @default.
• W4224229722 cites W2105249240 @default.
• W4224229722 cites W2132454074 @default.
• W4224229722 cites W2138857810 @default.
• W4224229722 cites W2149714065 @default.
• W4224229722 cites W230488438 @default.
• W4224229722 cites W2326592699 @default.
• W4224229722 cites W2334843210 @default.
• W4224229722 cites W2415028674 @default.
• W4224229722 cites W2466623356 @default.
• W4224229722 cites W249611194 @default.
• W4224229722 cites W2572753520 @default.
• W4224229722 cites W2588693507 @default.
• W4224229722 cites W2615180147 @default.
• W4224229722 cites W2888717733 @default.
• W4224229722 cites W2900105270 @default.
• W4224229722 cites W2949075875 @default.
• W4224229722 cites W2952910525 @default.
• W4224229722 cites W3083918058 @default.
• W4224229722 cites W3101301771 @default.
• W4224229722 cites W3216537544 @default.
• W4224229722 cites W4242647571 @default.
• W4224229722 cites W80260693 @default.
• W4224229722 doi "https://doi.org/10.1002/zaac.202200089" @default.
• W4224229722 hasPublicationYear "2022" @default.
• W4224229722 type Work @default.
• W4224229722 citedByCount "2" @default.
• W4224229722 countsByYear W42242297222022 @default.
• W4224229722 countsByYear W42242297222023 @default.
• W4224229722 crossrefType "journal-article" @default.
• W4224229722 hasAuthorship W4224229722A5032283210 @default.
• W4224229722 hasAuthorship W4224229722A5058070501 @default.
• W4224229722 hasConcept C115624301 @default.
• W4224229722 hasConcept C178790620 @default.
• W4224229722 hasConcept C185592680 @default.
• W4224229722 hasConcept C192562407 @default.
• W4224229722 hasConcept C198091228 @default.
• W4224229722 hasConcept C198819137 @default.
• W4224229722 hasConcept C199360897 @default.
• W4224229722 hasConcept C2781285689 @default.
• W4224229722 hasConcept C32909587 @default.
• W4224229722 hasConcept C41008148 @default.
• W4224229722 hasConcept C46000676 @default.
• W4224229722 hasConcept C544778455 @default.
• W4224229722 hasConcept C8010536 @default.
• W4224229722 hasConcept C81289067 @default.
• W4224229722 hasConcept C92840921 @default.
• W4224229722 hasConceptScore W4224229722C115624301 @default.
• W4224229722 hasConceptScore W4224229722C178790620 @default.
• W4224229722 hasConceptScore W4224229722C185592680 @default.
• W4224229722 hasConceptScore W4224229722C192562407 @default.
• W4224229722 hasConceptScore W4224229722C198091228 @default.
• W4224229722 hasConceptScore W4224229722C198819137 @default.
• W4224229722 hasConceptScore W4224229722C199360897 @default.
• W4224229722 hasConceptScore W4224229722C2781285689 @default.
• W4224229722 hasConceptScore W4224229722C32909587 @default.
• W4224229722 hasConceptScore W4224229722C41008148 @default.
• W4224229722 hasConceptScore W4224229722C46000676 @default.
• W4224229722 hasConceptScore W4224229722C544778455 @default.
• W4224229722 hasConceptScore W4224229722C8010536 @default.
• W4224229722 hasConceptScore W4224229722C81289067 @default.
• W4224229722 hasConceptScore W4224229722C92840921 @default.
• W4224229722 hasFunder F4320335937 @default.
• W4224229722 hasIssue "23" @default.
• W4224229722 hasLocation W42242297221 @default.
• W4224229722 hasOpenAccess W4224229722 @default.
• W4224229722 hasPrimaryLocation W42242297221 @default.
• W4224229722 hasRelatedWork W1971647987 @default.
• W4224229722 hasRelatedWork W1974006672 @default.
• W4224229722 hasRelatedWork W1984807283 @default.
• W4224229722 hasRelatedWork W2007775539 @default.
• W4224229722 hasRelatedWork W2028711677 @default.
• W4224229722 hasRelatedWork W2040749501 @default.
• W4224229722 hasRelatedWork W205471535 @default.
• W4224229722 hasRelatedWork W2089365959 @default.
• W4224229722 hasRelatedWork W2312786388 @default.
• W4224229722 hasRelatedWork W2989005193 @default.
• W4224229722 hasVolume "648" @default.
• W4224229722 isParatext "false" @default.
• W4224229722 isRetracted "false" @default.
• W4224229722 workType "article" @default.