Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224243014> ?p ?o ?g. }
- W4224243014 endingPage "12616" @default.
- W4224243014 startingPage "12610" @default.
- W4224243014 abstract "Palladium was immobilized on a highly porous copolymer of 4-vinylpyridine and divinylbenzene (polyHIPE-poly(high internal phase emulsion)) using palladium(II) acetate to obtain PolyPy-Pd with 6.1 wt % or 0.57 mmol Pd/g. The immobilized catalyst was able to catalyze the coupling of iodobenzene and phenylboronic acid in ethylene glycol monomethyl ether/water (3:1) within 4 h at rt and complete conversion was observed when 2.5 mol % of Pd per PhI was used. The reaction tolerated a wide range of substituents on the aromatic ring. Iodobenzene derivatives with electron-withdrawing substituents showed higher reactivity, while the opposite was true for the phenylboronic acid series. The polyHIPE-supported Pd catalyst was also used for the direct conversion of phenylboronic acid to biphenyl through an iodination/coupling reaction sequence. The recyclability of the heterogeneous catalyst was also optimized, and by finding a suitable combination of solvents for the loading of Pd, the reaction, and the isolation of the product, the solid-supported catalyst was completely regenerated and used in the next reaction with the same activity." @default.
- W4224243014 created "2022-04-26" @default.
- W4224243014 creator A5027272129 @default.
- W4224243014 creator A5042713992 @default.
- W4224243014 creator A5048410470 @default.
- W4224243014 creator A5069275655 @default.
- W4224243014 creator A5081685290 @default.
- W4224243014 creator A5081701870 @default.
- W4224243014 date "2022-04-06" @default.
- W4224243014 modified "2023-10-18" @default.
- W4224243014 title "Reusable Pd-PolyHIPE for Suzuki–Miyaura Coupling" @default.
- W4224243014 cites W118287225 @default.
- W4224243014 cites W1967968091 @default.
- W4224243014 cites W1973089281 @default.
- W4224243014 cites W1974119189 @default.
- W4224243014 cites W1974166089 @default.
- W4224243014 cites W1978890358 @default.
- W4224243014 cites W1979276942 @default.
- W4224243014 cites W1985558016 @default.
- W4224243014 cites W1989418488 @default.
- W4224243014 cites W2002025725 @default.
- W4224243014 cites W2004867175 @default.
- W4224243014 cites W2013760130 @default.
- W4224243014 cites W2027713965 @default.
- W4224243014 cites W2028431533 @default.
- W4224243014 cites W2044973933 @default.
- W4224243014 cites W2049392986 @default.
- W4224243014 cites W2057893978 @default.
- W4224243014 cites W2061343703 @default.
- W4224243014 cites W2061449541 @default.
- W4224243014 cites W2065988660 @default.
- W4224243014 cites W2069573662 @default.
- W4224243014 cites W2084335376 @default.
- W4224243014 cites W2087468424 @default.
- W4224243014 cites W2089185977 @default.
- W4224243014 cites W2098779029 @default.
- W4224243014 cites W2108789451 @default.
- W4224243014 cites W2116398931 @default.
- W4224243014 cites W2132752285 @default.
- W4224243014 cites W2138177542 @default.
- W4224243014 cites W2176364441 @default.
- W4224243014 cites W2180172928 @default.
- W4224243014 cites W2255034792 @default.
- W4224243014 cites W2564044301 @default.
- W4224243014 cites W2606177066 @default.
- W4224243014 cites W2793700613 @default.
- W4224243014 cites W2884449369 @default.
- W4224243014 cites W2899945894 @default.
- W4224243014 cites W2949147218 @default.
- W4224243014 cites W2950264938 @default.
- W4224243014 cites W2950974851 @default.
- W4224243014 cites W3047149329 @default.
- W4224243014 cites W3119226479 @default.
- W4224243014 cites W4361854982 @default.
- W4224243014 cites W2951851261 @default.
- W4224243014 doi "https://doi.org/10.1021/acsomega.1c06318" @default.
- W4224243014 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/35474763" @default.
- W4224243014 hasPublicationYear "2022" @default.
- W4224243014 type Work @default.
- W4224243014 citedByCount "3" @default.
- W4224243014 countsByYear W42242430142022 @default.
- W4224243014 countsByYear W42242430142023 @default.
- W4224243014 crossrefType "journal-article" @default.
- W4224243014 hasAuthorship W4224243014A5027272129 @default.
- W4224243014 hasAuthorship W4224243014A5042713992 @default.
- W4224243014 hasAuthorship W4224243014A5048410470 @default.
- W4224243014 hasAuthorship W4224243014A5069275655 @default.
- W4224243014 hasAuthorship W4224243014A5081685290 @default.
- W4224243014 hasAuthorship W4224243014A5081701870 @default.
- W4224243014 hasBestOaLocation W42242430142 @default.
- W4224243014 hasConcept C13205572 @default.
- W4224243014 hasConcept C161790260 @default.
- W4224243014 hasConcept C178790620 @default.
- W4224243014 hasConcept C185592680 @default.
- W4224243014 hasConcept C188027245 @default.
- W4224243014 hasConcept C2776451764 @default.
- W4224243014 hasConcept C2777516009 @default.
- W4224243014 hasConcept C2777734296 @default.
- W4224243014 hasConcept C2780591471 @default.
- W4224243014 hasConcept C48424934 @default.
- W4224243014 hasConcept C502130503 @default.
- W4224243014 hasConceptScore W4224243014C13205572 @default.
- W4224243014 hasConceptScore W4224243014C161790260 @default.
- W4224243014 hasConceptScore W4224243014C178790620 @default.
- W4224243014 hasConceptScore W4224243014C185592680 @default.
- W4224243014 hasConceptScore W4224243014C188027245 @default.
- W4224243014 hasConceptScore W4224243014C2776451764 @default.
- W4224243014 hasConceptScore W4224243014C2777516009 @default.
- W4224243014 hasConceptScore W4224243014C2777734296 @default.
- W4224243014 hasConceptScore W4224243014C2780591471 @default.
- W4224243014 hasConceptScore W4224243014C48424934 @default.
- W4224243014 hasConceptScore W4224243014C502130503 @default.
- W4224243014 hasFunder F4320322554 @default.
- W4224243014 hasIssue "15" @default.
- W4224243014 hasLocation W42242430141 @default.
- W4224243014 hasLocation W42242430142 @default.
- W4224243014 hasLocation W42242430143 @default.
- W4224243014 hasLocation W42242430144 @default.