Matches in SemOpenAlex for { <https://semopenalex.org/work/W4224253649> ?p ?o ?g. }
- W4224253649 abstract "Abstract A method of para ‐selective borylation of aromatic amides is described. The borylation proceeded via an unprecedented substrate–ligand distortion between the twisted aromatic amides and a newly designed ligand framework (defa) that is different from the traditionally used ligand (dtbpy) for the C−H borylation reactions. The designed ligand framework (defa) has led to the development of a new type of catalytic system that shows excellent para selectivity for a range of aromatic amides. Moreover, the designed ligand has shown excellent reactivity and selectivity for a range of heterocyclic aromatic amides. The identification of key transition states and intermediates using the DFT computations associated with the three regio‐isomeric pathways revealed that the most efficient catalytic pathway with the defa ligand leads to the para borylation while in the case of bpy the borylation at the para and meta sites compete." @default.
- W4224253649 created "2022-04-26" @default.
- W4224253649 creator A5014229329 @default.
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- W4224253649 creator A5072424884 @default.
- W4224253649 creator A5084124603 @default.
- W4224253649 date "2022-05-05" @default.
- W4224253649 modified "2023-09-26" @default.
- W4224253649 title "Iridium‐Catalyzed Ligand‐Controlled Remote <i>para</i>‐Selective C−H Activation and Borylation of Twisted Aromatic Amides" @default.
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