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• W4224256645 abstract "A facile and efficient route to dithiolanes starting from donor-acceptor cyclopropanes is reported. Potassium p-toluenethiosulfonate has been established as the reagent of choice for this formal insertion of the disulfide moiety. Using this methodology, dithiolanes have been synthesized in moderate to good yields with high functional group tolerance. Upon treatment with an excess of mCPBA, the corresponding dithiolanes delivered four-membered thietane dioxides, the formal (3+1)-cycloaddition product of D-A cyclopropanes, and sulfur dioxide." @default.
• W4224256645 created "2022-04-26" @default.
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• W4224256645 date "2022-04-20" @default.
• W4224256645 modified "2023-10-17" @default.
• W4224256645 title "Insertion of S₂ into Donor–Acceptor Cyclopropanes: Access to Dithiolanes and Their Conversion to Thietane Dioxides" @default.
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• W4224256645 doi "https://doi.org/10.1021/acs.orglett.2c00967" @default.
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