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- W4224257412 abstract "Transition metal oxide/metal–organic framework heterojunctions ([email protected]) that combine the large specific surface area of MOFs with TMOs' high catalytic activity and multifunctionality, show excellent performances in various catalytic reactions. Nevertheless, the present preparation approaches of [email protected] heterojunctions are too complex to control, stimulating interests in developing simple and highly controllable methods for preparing such heterojunction. In this study, we propose an in situ electrochemical reduction approach to fabricating Cu2O nanoparticle (NP)@CuHHTP heterojunction nanoarrays with a graphene-like conductive MOF CuHHTP (HHTP is 2,3,6,7,10,11-hexahydroxytriphenylene). We have discovered that size-controlled Cu2O nanoparticles could be in situ grown on CuHHTP by applying different electrochemical reduction potentials. Also, the obtained Cu2O [email protected] heterojunction nanoarrays show high H2O2 sensitivity of 8150.6 μA·mM−1·cm2 and satisfactory detection performances in application of measuring H2O2 concentrations in urine and serum samples. This study offers promising guidance for the synthesis of MOF-based heterojunctions for early cancer diagnosis." @default.
- W4224257412 created "2022-04-26" @default.
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- W4224257412 date "2022-09-01" @default.
- W4224257412 modified "2023-10-16" @default.
- W4224257412 title "In situ electrochemical reductive construction of metal oxide/metal-organic framework heterojunction nanoarrays for hydrogen peroxide sensing" @default.
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- W4224257412 doi "https://doi.org/10.1016/j.jcis.2022.04.095" @default.
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