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- W4224264911 abstract "The vapochromic single-crystal-to-single-crystal (SCSC) transformation of a highly luminescent PtII complex bearing an N-heterocyclic carbene [Pt(CN)2 (tBu-impy)] (tBu-impyH+ =1-tert-butyl-3-(2-pyridyl)-1H-imidazolium) is reported. The trihydrate form of the complex, which exhibits blue 3 MMLCT emission owing to weak Pt⋅⋅⋅Pt interactions, changed its luminescence color from blue to yellowish-green upon the desorption of water molecules while keeping the high emission quantum yield of more than 0.45. Variable-temperature and continuous in-situ tracking of single-crystal X-ray diffraction measurements revealed that the SCSC transformation proceeds reversibly by the release and reabsorption of water molecules, thereby changing the stacked structure slightly. As a result, the dynamics of vapor-induced SCSC transformation were elucidated: that the anhydrous form returned to the original trihydrate form in a two-step process under a water vapor atmosphere. In addition, the PtII complex exhibited a similar SCSC response accompanied by a luminescence color change in the presence of methanol vapor, while being inactive toward ethanol vapor." @default.
- W4224264911 created "2022-04-26" @default.
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- W4224264911 date "2022-05-11" @default.
- W4224264911 modified "2023-10-16" @default.
- W4224264911 title "Reversible and Stepwise Single‐Crystal‐to‐Single‐Crystal Transformation of a Platinum(II) Complex with Vapochromic Luminescence" @default.
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- W4224264911 doi "https://doi.org/10.1002/chem.202200703" @default.
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