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- W4224274311 abstract "Abstract 9,10‐Dihydro‐9‐oxa‐10‐phosphaphenanthrene (DOPO) is the star product in flame retard of epoxy resin (EP). However, its limited production capacity can hardly meet the market demand. In this work, a new phosphorus‐containing flame retardant named as methanephosphonite (MTA) was successfully synthesized to substitute the DOPO in EP. Due to the supreme efficiency of the gas phase mechanism, only 1.5 wt% of phosphorus is sufficient to achieve V0 rating and the LOI is as high as 31.4%. In addition, MTA can effectively suppress the heat release during combustion, and the peak of the heat release rate (pk‐HRR) of the MTA/EP‐2.0 decreases 50% than that of neat EP. Besides, the introduction of MTA does not significantly deteriorate the mechanical properties of the thermoset MTA/EP‐1.5, both of the flexural strength and impact strength reduce less than 15%, which shows a great value for EP material." @default.
- W4224274311 created "2022-04-26" @default.
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- W4224274311 date "2022-04-19" @default.
- W4224274311 modified "2023-10-14" @default.
- W4224274311 title "A novel phosphorus compound acting as a substitute of <scp>DOPO</scp> for flame retard of epoxy resin" @default.
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- W4224274311 doi "https://doi.org/10.1002/app.52426" @default.
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