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• W4224282511 endingPage "3096" @default.
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• W4224282511 abstract "Treatment of 4-(2-hydroaminoalkylidenyl)- and 4-(2-hydroxyalkylidenyl)-substituted isoxazol-5(4H)-ones with catalytic amounts of [RuCl2(p-cymene)]2, without any additive, afforded pyrazole- and isoxazole-4-carboxylic acids, respectively. The presence of an intramolecular H-bond in these substrates was the key to divert the classical mechanism toward a ring-opening non-decarboxylative path that is expected to generate a vinyl Ru-nitrenoid intermediate, the cyclization of which affords the rearranged products. A gram scale protocol demonstrated the synthetic applicability of this transformation." @default.
• W4224282511 created "2022-04-26" @default.
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• W4224282511 date "2022-04-19" @default.
• W4224282511 modified "2023-09-26" @default.
• W4224282511 title "Non-Decarboxylative Ruthenium-Catalyzed Rearrangement of 4-Alkylidene-isoxazol-5-ones to Pyrazole- and Isoxazole-4-carboxylic Acids" @default.
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• W4224282511 doi "https://doi.org/10.1021/acs.orglett.2c01135" @default.
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